Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Organic Chemistry >  Hydrocarbons and derivatives >  Hydrocarbon halides >  4-Bromo-1-butene

4-Bromo-1-butene

Basic information Safety Supplier Related

4-Bromo-1-butene Basic information

Product Name:
4-Bromo-1-butene
Synonyms:
  • 1-Bromo-3-butene
  • 1-butene,4-bromo-
  • 3-BUTENYL BROMIDE
  • 4-BROMO-1-BUTENE, STAB.
  • 4-Bromo-1-butene, 98+%
  • 4-Bromo-1-butene, GC 98%
  • 4-bromo-1-buten
  • 4-bromo-but-1-ene
CAS:
5162-44-7
MF:
C4H7Br
MW:
135
EINECS:
225-937-4
Product Categories:
  • Building Blocks
  • Chemical Synthesis
  • omega-Functional Alkanols, Carboxylic Acids, Amines & Halides
  • omega-Unsaturated Halides
  • Halogenated Hydrocarbons
  • Organic Building Blocks
  • Halides
  • Alkenyl
  • Halogenated Hydrocarbons
  • Organic Building Blocks
  • bc0001
Mol File:
5162-44-7.mol
More
Less

4-Bromo-1-butene Chemical Properties

Melting point:
-115.07°C (estimate)
Boiling point:
98-100 °C (lit.)
Density 
1.33 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.462(lit.)
Flash point:
49 °F
storage temp. 
Store below +30°C.
solubility 
0.76g/l
form 
Liquid
color 
Clear colorless to light brownish
Specific Gravity
1.330
Water Solubility 
Miscible with water, benzene, ether and ethanol.
Sensitive 
Light Sensitive
BRN 
1098377
Stability:
Stable. Incompatible with strong bases, strong oxidizing agents. Highly flammable. Light sensitive.
InChIKey
DMAYBPBPEUFIHJ-UHFFFAOYSA-N
CAS DataBase Reference
5162-44-7(CAS DataBase Reference)
NIST Chemistry Reference
1-Butene, 4-bromo-(5162-44-7)
EPA Substance Registry System
1-Butene, 4-bromo- (5162-44-7)
More
Less

Safety Information

Hazard Codes 
F,Xn,Xi
Risk Statements 
11-36/37-42/43
Safety Statements 
26-36/37/39
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
8-19
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29033036

MSDS

More
Less

4-Bromo-1-butene Usage And Synthesis

Chemical Properties

colourless liquid

Uses

4-Bromo-1-butene is a brominated alkene used as a reagent in organic synthesis.

Uses

4-Bromo-1-butene is used in the preparation of 4-(3-butenyloxy)benzoic acid and largazole. It is also used in double alkylation of lactams followed by Grubbs ring-closing metathesis to yield gymnodimine. Further, it serves as a reagent in the preparation of dienehydrazides.

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 251, 1984 DOI: 10.1016/S0040-4039(00)99853-8

General Description

Stereoselective epoxidation of 4-bromo-1-butene was carried out with three alkene-utilizing bacteria: Mycobacterium LI, Mycobacterium E3 and Nocardia IP1.

4-Bromo-1-buteneSupplier

Anqing PhiChem Corporation Gold
Tel
0556-5209970
Email
salesaq@phichem.com.cn
Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd. Gold
Tel
133-96369453 18678026865
Email
sdfantai@163.com
Shanghai Jinsai Biotechnology Co., LTD Gold
Tel
13681638167 13681638167
Email
zouxiao8466@163.com
Aikon International Limited Gold
Tel
025-66028182 18112977050
Email
cfzhang@aikonchem.com
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. Gold
Tel
025-66113011 18112977050
Email
cb6@aikonchem.com