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Tetraethylammonium tetrafluoroborate

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Tetraethylammonium tetrafluoroborate Basic information

Product Name:
Tetraethylammonium tetrafluoroborate
Synonyms:
  • TetraethylaMMoniuM tetrafluoroborate, 99% 25GR
  • TETRAETHYLAMMONIUM TETRAFLUOROBORATE FOR
  • TEATFB
  • Tetraethylammonium tetrafluoroboratee
  • N2,2,2,2BF4
  • TETRAETHYLAMMONIUM TETRAFLUOROBORATE
  • TETRAETHYLAMMONIUM FLUOROBORATE
  • Ethanaminium, N,N,N-triethyl-, tetrafluoroborate(1-)
CAS:
429-06-1
MF:
C8H20BF4N
MW:
217.06
EINECS:
207-055-1
Product Categories:
  • Greener Alternatives: Catalysis
  • Phase Transfer Catalysts
  • Supporting Electrolytes for Electrochemistry
  • Ammonium SaltsMetal and Ceramic Science
  • Ammonium Salts
  • Salts
  • Ammonium Polyhalides, etc. (Quaternary)
  • B (Classes of Boron Compounds)
  • Quaternary Ammonium Compounds
  • Tetrafluoroborates
  • Ammonium SaltsAnalytical Reagents
  • Electrochemistry
Mol File:
429-06-1.mol
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Tetraethylammonium tetrafluoroborate Chemical Properties

Melting point:
≥300 °C(lit.)
Density 
1.23 at 20℃
vapor pressure 
0-0Pa at 20-25℃
storage temp. 
Store below +30°C.
solubility 
acetonitrile: 0.1 g/mL, clear, colorless
form 
Crystals or Crystalline Powder
color 
White
Water Solubility 
Soluble in water, alcohol and acetonitrile.
Sensitive 
Hygroscopic
BRN 
3917638
InChIKey
VDMMJVHZGWXBJN-UHFFFAOYSA-M
LogP
-3.5 at 20.2℃ and pH7
Surface tension
72.07mN/m at 1g/L and 20℃
CAS DataBase Reference
429-06-1(CAS DataBase Reference)
EPA Substance Registry System
Ethanaminium, N,N,N-triethyl-, tetrafluoroborate(1-) (429-06-1)
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Safety Information

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
RIDADR 
2811
WGK Germany 
3
Hazard Note 
Irritant/Hygroscopic
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29239000

MSDS

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Tetraethylammonium tetrafluoroborate Usage And Synthesis

Chemical Properties

white crystals or crystalline powder

Uses

Tetraethylammonium Tetrafluoroborate is used in the preparation of some organic salts of fluoboric acids.

General Description

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Purification Methods

Dissolve the salt in hot MeOH, filter and add Et2O. It is soluble in ethylene chloride [Thompson & Kraus J Am Chem Soc 69 1016 1947, Wheeler & Sandstadt 77 2025 1955]. It has also been recrystallised three times from a mixture of ethyl acetate/hexane (5:1) or MeOH/pet ether, then stored at 95o for 48hours under vacuum [Henry & Faulkner J Am Chem Soc 107 3436 1985, Huang et al. Anal Chem 58 2889 1986]. It is used as a supporting electrolyte. [Beilstein 4 IV 333.]

Tetraethylammonium tetrafluoroborate Preparation Products And Raw materials

Raw materials

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