ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Sulfonates / Sulfinates salts > 4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt
4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt
4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt Basic information
- Product Name:
- 4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt
- Synonyms:
-
- P-CHLOROMERCURIPHENYLSULFONIC ACID
- PCMBS
- 4-(chloromercuri)benzenesulfonic acid monosodium salt
- P-chloromercuriphenylsulfonic acid*monosodium
- sodium 4-(chloromercurio)benzenesulphonate
- 4-(Chloromercuri)benzenesulfonic ,sodium salt
- 4-(CHLOROMERCURI)BENZENESULFONIC ACID, SODIUM SALT
- p-Chloromercuriphenylsulfonic Acid, PCMBS
- CAS:
- 14110-97-5
- MF:
- C6H4ClHgNaO3S
- MW:
- 415.19
- Product Categories:
-
- MTS and Sulfhydryl Active Reagents
- MTS & Sulfhydryl Active Reagents
- Aromatics
- Mol File:
- 14110-97-5.mol
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4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt Chemical Properties
- Melting point:
- >370°C
- storage temp.
- Amber Vial, -20°C Freezer
- solubility
- DMSO (Slightly, Heated), Water (Slightly)
- form
- Solid
- color
- Off-White to Light Grey
- Stability:
- Store at -20°C
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Safety Information
- Hazard Codes
- T
- RIDADR
- 2025
- Hazard Note
- Toxic
- HazardClass
- 6.1(a)
- PackingGroup
- II
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4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt Usage And Synthesis
Chemical Properties
Off-White Powder
Uses
A useful sulfhydryl reagent, 4-(ChloroMercuri)benzenesulfonic Acid SodiuM Salt reacts with Histidine 225C, a residue of the NhaA-Na/H Antiporter of Escherichia Coli. More soluble than p-chloromercuribenzoic acid
Purification Methods
The free acid is obtained by acidifying an aqueous solution, filtering off the acid, washing it with H2O and recrystallising from hot H2O to give a colourless solid which is dried in a vacuum over P2O5 and should be free of Cl-ions (AgNO3 test). The Na salt is made by dissolving it in one equivalent of aqueous NaOH and evaporating to dryness. [Nesmejanow et al. Chem Ber 67 130 1934, Boyer J Am Chem Soc 76 4331 1954.] HIGHLY TOXIC.
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