(1R)-(-)-Nopol
(1R)-(-)-Nopol Basic information
- Product Name:
- (1R)-(-)-Nopol
- Synonyms:
-
- (1R)-6,6-DIMETHYLBICYCLO[3.1.1]HEPT-2-ENE-2-ETHANOL
- Dimethylbicyclohepteneethanol
- (1R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-ethanol
- 6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL
- 6,6-DIMETHYL-2-NORPINENE-2-ETHANOL
- Bicyclo3.1.1hept-2-ene-2-ethanol, 6,6-dimethyl-, (1R,5S)-
- (-)-Nopol, (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol, 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol
- (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol
- CAS:
- 35836-73-8
- MF:
- C11H18O
- MW:
- 166.26
- EINECS:
- 252-744-2
- Mol File:
- 35836-73-8.mol
(1R)-(-)-Nopol Chemical Properties
- Boiling point:
- 235-236 °C(lit.)
- Density
- 0.973 g/mL at 25 °C(lit.)
- vapor pressure
- 2.17Pa at 20℃
- refractive index
- n20/D 1.493
- Flash point:
- 210 °F
- storage temp.
- Refrigerator, under inert atmosphere
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Oil
- pka
- 15.03±0.10(Predicted)
- color
- Clear Colourless
- optical activity
- [α]24/D 37°, neat
- Water Solubility
- 333.5mg/L at 20℃
- Merck
- 14,6683
- BRN
- 3196379
- LogP
- 3.09 at 30℃
Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26-37/39
- WGK Germany
- 3
- RTECS
- RC8870000
- HS Code
- 29061900
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
(1R)-(-)-Nopol Usage And Synthesis
Chemical Properties
Clear colorless to light yellow liquid
Uses
(-)-Nopol, is a chiral building block used in chemical synthesis. It is an intermediate that can be used for the synthesis of bulky moiety-modified analogs to the sandalwood odorant Polysantol.
Definition
ChEBI: (-)-Nopol is a monoterpenoid.
Application
(1R)-(-)-Nopol may be used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids by reacting with tetraphosphorus decasulfide and 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides, respectively. It may also react with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization.
General Description
(1R)-(-)-Nopol is a chiral terpenol derivative.
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