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(1R)-(-)-Nopol

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(1R)-(-)-Nopol Basic information

Product Name:
(1R)-(-)-Nopol
Synonyms:
  • (1R)-6,6-DIMETHYLBICYCLO[3.1.1]HEPT-2-ENE-2-ETHANOL
  • Dimethylbicyclohepteneethanol
  • (1R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-ethanol
  • 6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL
  • 6,6-DIMETHYL-2-NORPINENE-2-ETHANOL
  • Bicyclo3.1.1hept-2-ene-2-ethanol, 6,6-dimethyl-, (1R,5S)-
  • (-)-Nopol, (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol, 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol
  • (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol
CAS:
35836-73-8
MF:
C11H18O
MW:
166.26
EINECS:
252-744-2
Mol File:
35836-73-8.mol
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(1R)-(-)-Nopol Chemical Properties

Boiling point:
235-236 °C(lit.)
Density 
0.973 g/mL at 25 °C(lit.)
vapor pressure 
2.17Pa at 20℃
refractive index 
n20/D 1.493
Flash point:
210 °F
storage temp. 
Refrigerator, under inert atmosphere
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Oil
pka
15.03±0.10(Predicted)
color 
Clear Colourless
optical activity
[α]24/D 37°, neat
Water Solubility 
333.5mg/L at 20℃
Merck 
14,6683
BRN 
3196379
LogP
3.09 at 30℃
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22-36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
RTECS 
RC8870000
HS Code 
29061900

MSDS

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(1R)-(-)-Nopol Usage And Synthesis

Chemical Properties

Clear colorless to light yellow liquid

Uses

(-)-Nopol, is a chiral building block used in chemical synthesis. It is an intermediate that can be used for the synthesis of bulky moiety-modified analogs to the sandalwood odorant Polysantol.

Definition

ChEBI: (-)-Nopol is a monoterpenoid.

Application

(1R)-(-)-Nopol may be used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids by reacting with tetraphosphorus decasulfide and 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides, respectively. It may also react with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization.

General Description

(1R)-(-)-Nopol is a chiral terpenol derivative.

(1R)-(-)-NopolSupplier

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