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MOLYBDENUM(VI) DICHLORIDE DIOXIDE

Basic information Description Reference Safety Supplier Related

MOLYBDENUM(VI) DICHLORIDE DIOXIDE Basic information

Product Name:
MOLYBDENUM(VI) DICHLORIDE DIOXIDE
Synonyms:
  • Molybdenum chloride oxide
  • MoO2Cl2
  • MOLYBDENUM(VI) DICHLORIDE DIOXIDE
  • MOLYBDENUM DIOXY DICHLORIDE
  • MOLYBDENUM DICHLORIDE DIOXIDE
  • MOLYBDENUM DICHLORIDE OXIDE
  • Molybdenum dichloride dioxide, Cl 34% min
  • Dichlorodioxomolybdenum(VI)
CAS:
13637-68-8
MF:
Cl2MoO2
MW:
198.84
Product Categories:
  • Metal and Ceramic Science
  • Molybdenum Salts
  • Salts
Mol File:
13637-68-8.mol
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MOLYBDENUM(VI) DICHLORIDE DIOXIDE Chemical Properties

Melting point:
184(subl.)
Density 
3.31 g/mL at 25 °C(lit.)
solubility 
reacts with H2O
form 
yellow-orange solid
color 
yellow-orange
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Safety Information

Hazard Codes 
C,Xi
Risk Statements 
34
Safety Statements 
26-27-36/37/39-45
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
III
HS Code 
2827499090

MSDS

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MOLYBDENUM(VI) DICHLORIDE DIOXIDE Usage And Synthesis

Description

Molybdenum is much less toxic than typical heavy metals and already found application as an alternative substitute for some heavy metals. Molybdenum has also found application in materials like pigments, corrosion inhibitors, smoke suppressants, lubricants and fertilizers. Molybdenum dichloride dioxide has strong application as a kind of catalyst in organic transformation. Molybdenum Dichloride Dioxide can be used to catalyze carbamate formation from an alcohol and isocyanates, acylation reactions, thioglycosylation of functionalized peracetylated glycosides, hydrosilylation of aldehydes and ketones as well as reduction of many compounds like imines, esters, amides and N-oxides. It is also used to catalyze the oxidation of sulfides, thiols as well as the synthesis of beta-keto esters and thiocaetalization of aldehydes. It can also be used to analyze the antioxidant in solder plating solutions.

Reference

  1. Stock, C., & Brückner, R. (2010) Synlett, 2010(16), 2429-2434.
  2. KING, Mackenzie, SCHOMBURG, Cory, HILGARTH, & Monica. (2005). Analysis of antioxidant in solder plating solutions using molybdenum dichloride dioxide.
  3. Jeyakumar, Kandasamy, and D. K. Chand. Journal of Chemical Sciences 121.2(2009):111-123.

Chemical Properties

yellowish-orange solid [LID94]

Uses

Molybdenum(VI) Dichloride Dioxide can be used as electrolytes for secondary lithium batteries.

MOLYBDENUM(VI) DICHLORIDE DIOXIDESupplier

Shaanxi Dideu Medichem Co. Ltd Gold
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