MOLYBDENUM(VI) DICHLORIDE DIOXIDE
MOLYBDENUM(VI) DICHLORIDE DIOXIDE Basic information
- Product Name:
- MOLYBDENUM(VI) DICHLORIDE DIOXIDE
- Synonyms:
-
- Molybdenum chloride oxide
- MoO2Cl2
- MOLYBDENUM(VI) DICHLORIDE DIOXIDE
- MOLYBDENUM DIOXY DICHLORIDE
- MOLYBDENUM DICHLORIDE DIOXIDE
- MOLYBDENUM DICHLORIDE OXIDE
- Molybdenum dichloride dioxide, Cl 34% min
- Dichlorodioxomolybdenum(VI)
- CAS:
- 13637-68-8
- MF:
- Cl2MoO2
- MW:
- 198.84
- Product Categories:
-
- Metal and Ceramic Science
- Molybdenum Salts
- Salts
- Mol File:
- 13637-68-8.mol
MOLYBDENUM(VI) DICHLORIDE DIOXIDE Chemical Properties
- Melting point:
- 184(subl.)
- Density
- 3.31 g/mL at 25 °C(lit.)
- solubility
- reacts with H2O
- form
- yellow-orange solid
- color
- yellow-orange
Safety Information
- Hazard Codes
- C,Xi
- Risk Statements
- 34
- Safety Statements
- 26-27-36/37/39-45
- RIDADR
- UN 3260 8/PG 2
- WGK Germany
- 3
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 2827499090
MSDS
- Language:English Provider:SigmaAldrich
MOLYBDENUM(VI) DICHLORIDE DIOXIDE Usage And Synthesis
Description
Molybdenum is much less toxic than typical heavy metals and already found application as an alternative substitute for some heavy metals. Molybdenum has also found application in materials like pigments, corrosion inhibitors, smoke suppressants, lubricants and fertilizers. Molybdenum dichloride dioxide has strong application as a kind of catalyst in organic transformation. Molybdenum Dichloride Dioxide can be used to catalyze carbamate formation from an alcohol and isocyanates, acylation reactions, thioglycosylation of functionalized peracetylated glycosides, hydrosilylation of aldehydes and ketones as well as reduction of many compounds like imines, esters, amides and N-oxides. It is also used to catalyze the oxidation of sulfides, thiols as well as the synthesis of beta-keto esters and thiocaetalization of aldehydes. It can also be used to analyze the antioxidant in solder plating solutions.
Reference
- Stock, C., & Brückner, R. (2010) Synlett, 2010(16), 2429-2434.
- KING, Mackenzie, SCHOMBURG, Cory, HILGARTH, & Monica. (2005). Analysis of antioxidant in solder plating solutions using molybdenum dichloride dioxide.
- Jeyakumar, Kandasamy, and D. K. Chand. Journal of Chemical Sciences 121.2(2009):111-123.
Chemical Properties
yellowish-orange solid [LID94]
Uses
Molybdenum(VI) Dichloride Dioxide can be used as electrolytes for secondary lithium batteries.
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