ALLYLDIPHENYLPHOSPHINE OXIDE Chemical Properties

Melting point:

110-114 °C(lit.)

Boiling point:

200-202 °C(Press: 2 Torr)

Density 

1.0769 g/cm3

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

solid

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

MSDS

• Language:English Provider:SigmaAldrich

ALLYLDIPHENYLPHOSPHINE OXIDE Usage And Synthesis

Uses

Reactant for:

• Preparaton of a-substituted alkylsilanes via regio- and chemoselective copper-catalyzed silylzincation and electrophilic substitution from terminal alkenes, and prepn. of α-substituted alcohols via Fleming-Tamao oxidation of alkylsilanes
• Olefin isomerization with Grubbs′ catalysts occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS)
• C9-substituted trans-hydrindene via diastereotopic group-selective intramolecular Diels-Alder reaction
• Isomerization of allyl group-containing compounds to propenyl group-containing compounds in the presence of a Grubbs second-generation Ru catalyst
• Ruthenium-catalyzed olefin cross-metathesis of vinyl and allyl phosphine oxides to give alkenyl phosphine oxides and bis-phosphine oxides

ALLYLDIPHENYLPHOSPHINE OXIDE(4141-48-4)Related Product Information

• ALLYLDIPHENYLPHOSPHINE
• Allylboronic acid pinacol ester
• ALLYLTRIETHOXYSILANE
• Probenazole
• Allicin
• ALLYLUREA
• Diethyl allylmalonate
• Allylbenzene
• Allyl Benzyl Ether
• Dimethyl allylmalonate
• Allyl methyl carbonate
• DIETHYL ALLYLPHOSPHONATE
• 1-allylhydrazine hydrochloride
• Allylhydrazine Dihydrochloride
• ALLYLHYDRAZINE
• 2-Allyloxyethanol
• Diphenylphosphine oxide
• ALLYLDIPHENYLPHOSPHINE OXIDE