n-Butylboronic acid
n-Butylboronic acid Basic information
- Product Name:
- n-Butylboronic acid
- Synonyms:
-
- 1-(dihydroxyboryl)butane
- 1-BUTANEBORONIC ACID
- 1-BUTYLBORONIC ACID
- BUTYLBORIC ACID
- BUTYLBORONIC ACID
- N-BUTYLBORONIC ACID
- NBBA
- N-BUTANEBORONIC ACID
- CAS:
- 4426-47-5
- MF:
- C4H11BO2
- MW:
- 101.94
- EINECS:
- 224-607-7
- Product Categories:
-
- Boronic Acid
- blocks
- BoronicAcids
- Boronic Acid, etc. (GC Derivatizing Reagents)
- Analytical Chemistry
- B (Classes of Boron Compounds)
- Boronic Acids
- GC Derivatizing Reagents
- CHIRAL CHEMICALS
- Mol File:
- 4426-47-5.mol
n-Butylboronic acid Chemical Properties
- Melting point:
- 90-92 °C(lit.)
- Boiling point:
- 189.2±23.0 °C(Predicted)
- Density
- 1.022 g/cm3
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- solubility
- DMSO (Slightly), Methanol (Slightly)
- pka
- 10.37±0.43(Predicted)
- form
- Liquid
- color
- Clear colorless to slightly yellow
- Water Solubility
- ca 2.5 g/100 mL
- Sensitive
- Air Sensitive & Hygroscopic
- BRN
- 1733489
- InChIKey
- QPKFVRWIISEVCW-UHFFFAOYSA-N
- CAS DataBase Reference
- 4426-47-5(CAS DataBase Reference)
Safety Information
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-20/21/22
- Safety Statements
- 22-24/25-37/39-26-36
- WGK Germany
- 3
- F
- 3-10-23
- TSCA
- No
- HazardClass
- IRRITANT
- HS Code
- 29319090
MSDS
- Language:English Provider:n-Butylboronic acid
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
n-Butylboronic acid Usage And Synthesis
Chemical Properties
white to faintly beige shinying platelets
Uses
1-Butylboronic acid is used as a reagent for preparation of volatile derivatives of diols, e.g. carbohydrates, for GC and mass spectrometry and to prepare chiral oxazaborolidines. It is a precursor to unsymmetric borinic acids, which are inhibitors of serine proteases. Can be used as a transport carrier in membrane-based sugar separations and as an analytical reagent in the determination of serum glucose.
Uses
n-Butylboronic acid is a boronic acid derivative that can be used as a transport carriers in membrane-based sugar separations. n-Butylboronic acid is used as an analytical reagent in the determination of serum glucose.
Uses
n-Butylboronic acid can be used in suzuki reaction.
Purification Methods
Butylboronic acid (1-butanedihydroxyborane) [4426-47-5] M 101.9, m 90 -92o, 94 -96o, pKEst ~8.8.acuo. [Corey et al. J Am Chem Soc 116 3151 1994, Quallich et al. J Am Chem Soc 116 8515 1994, Seerden Tetrahedron Lett 35 4419 1994, Beilstein 4 IV 4383.]
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