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n-Butylboronic acid

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n-Butylboronic acid Basic information

Product Name:
n-Butylboronic acid
Synonyms:
  • 1-(dihydroxyboryl)butane
  • 1-BUTANEBORONIC ACID
  • 1-BUTYLBORONIC ACID
  • BUTYLBORIC ACID
  • BUTYLBORONIC ACID
  • N-BUTYLBORONIC ACID
  • NBBA
  • N-BUTANEBORONIC ACID
CAS:
4426-47-5
MF:
C4H11BO2
MW:
101.94
EINECS:
224-607-7
Product Categories:
  • Boronic Acid
  • blocks
  • BoronicAcids
  • Boronic Acid, etc. (GC Derivatizing Reagents)
  • Analytical Chemistry
  • B (Classes of Boron Compounds)
  • Boronic Acids
  • GC Derivatizing Reagents
  • CHIRAL CHEMICALS
Mol File:
4426-47-5.mol
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n-Butylboronic acid Chemical Properties

Melting point:
90-92 °C(lit.)
Boiling point:
189.2±23.0 °C(Predicted)
Density 
1.022 g/cm3
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
DMSO (Slightly), Methanol (Slightly)
pka
10.37±0.43(Predicted)
form 
Liquid
color 
Clear colorless to slightly yellow
Water Solubility 
ca 2.5 g/100 mL
Sensitive 
Air Sensitive & Hygroscopic
BRN 
1733489
InChIKey
QPKFVRWIISEVCW-UHFFFAOYSA-N
CAS DataBase Reference
4426-47-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
22-24/25-37/39-26-36
WGK Germany 
3
3-10-23
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29319090

MSDS

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n-Butylboronic acid Usage And Synthesis

Chemical Properties

white to faintly beige shinying platelets

Uses

1-Butylboronic acid is used as a reagent for preparation of volatile derivatives of diols, e.g. carbohydrates, for GC and mass spectrometry and to prepare chiral oxazaborolidines. It is a precursor to unsymmetric borinic acids, which are inhibitors of serine proteases. Can be used as a transport carrier in membrane-based sugar separations and as an analytical reagent in the determination of serum glucose.

Uses

n-Butylboronic acid is a boronic acid derivative that can be used as a transport carriers in membrane-based sugar separations. n-Butylboronic acid is used as an analytical reagent in the determination of serum glucose.

Uses

n-Butylboronic acid can be used in suzuki reaction.

Purification Methods

Butylboronic acid (1-butanedihydroxyborane) [4426-47-5] M 101.9, m 90 -92o, 94 -96o, pKEst ~8.8.acuo. [Corey et al. J Am Chem Soc 116 3151 1994, Quallich et al. J Am Chem Soc 116 8515 1994, Seerden Tetrahedron Lett 35 4419 1994, Beilstein 4 IV 4383.]

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