2-Chloro-4-methylpyrimidine Chemical Properties

Melting point:

35-36°C

Boiling point:

94°C/17mmHg(lit.)

Density 

1.234±0.06 g/cm3(Predicted)

Flash point:

98℃

storage temp. 

Keep in dark place,Sealed in dry,Room Temperature

solubility 

Chloroform

form 

Solid

pka

-0.93±0.20(Predicted)

color 

Pale Yellow to Beige

Sensitive 

Moisture Sensitive

Stability:

Toxic

InChI

InChI=1S/C5H5ClN2/c1-4-2-3-7-5(6)8-4/h2-3H,1H3

InChIKey

BHAKRVSCGILCEW-UHFFFAOYSA-N

SMILES

C1(Cl)=NC=CC(C)=N1

CAS DataBase Reference

13036-57-2(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi,Xn

Risk Statements 

22-41-37/38

Safety Statements 

26-39

WGK Germany 

3

TSCA 

N

HazardClass 

IRRITANT

HS Code 

29335990

2-Chloro-4-methylpyrimidine Usage And Synthesis

Chemical Properties

Pale Yellow Solid

Uses

2-Chloro-4-methylpyrimidine (cas# 13036-57-2) is a compound useful in organic synthesis.

Application

2-chloro-4-methylpyrimidine could be used to synthesis 4-Methyl-2-vinylpyrimidine which is a intermediate of pyrimidinyl trans-cyclopropane carboxylic acid (rac-1)[1].

References

[1] M. Fray. “N-Ylide Mediated Synthesis and Resolution of a Chiral Pyrimidinyl Cyclopropane Carboxylic Acid.” Organic Process Research &Development 19 1 (2023).

2-Chloro-4-methylpyrimidine(13036-57-2)Related Product Information

• 4-Methylpyridine
• 2,5-Dimethylpyridine
• 2,6-Lutidine
• 2-Chloro-4-nitropyridine
• Chromium picolinate
• 2,4,6-Collidine
• 2-chloro-6-trichloromethylpyridine
• 2-(Chloromethyl)pyridine
• 2-CHLORO-4-METHYL-THIAZOLE
• Methyl 2-chloro-4-(trifluoromethyl)pyrimidine-5-carboxylate
• 2,4-Dichloro-6-methyl-5-nitropyrimidine
• 2-CHLORO-4-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBONYL CHLORIDE
• 2-Chloro-4-(trifluoromethyl)pyrimidine
• CRIMIDINE
• 2-Chloro-4,6-dimethylpyrimidine
• 2,4-Dichloro-6-methylpyrimidine
• METHYL 2-CHLORO-6-METHYLPYRIMIDINE-4-CARBOXYLATE,Methyl 2-chloro-4-methylpyrimidine-6-carboxylate, HPLC +97%
• Difluorochloromethane