1H,1H,2H,2H-Perfluorooctyltrichlorosilane Chemical Properties

Melting point:

-32°C

Boiling point:

192 °C(lit.)

Density 

1.3 g/mL at 25 °C(lit.)

vapor pressure 

0.007-30Pa at 25℃

refractive index 

n20/D 1.352(lit.)

Flash point:

189 °F

solubility 

Miscible with tetrahydrofuran, tetrhydropyran, toluene and other organic solvents.

form 

clear liquid

Specific Gravity

1.3

color 

Colorless to Almost colorless

Water Solubility 

580μg/L at 20℃

Sensitive 

Moisture Sensitive

Hydrolytic Sensitivity

8: reacts rapidly with moisture, water, protic solvents

BRN 

6154526

Stability:

Stable. Highly flammable. Incompatible with strong oxidizing agents, water, alcohols, bases.

InChIKey

PISDRBMXQBSCIP-UHFFFAOYSA-N

LogP

2.7 at 20℃

CAS DataBase Reference

78560-45-9(CAS DataBase Reference)

EPA Substance Registry System

Trichloro((perfluorohexyl)ethyl)silane (78560-45-9)

Safety Information

Hazard Codes 

C

Risk Statements 

14-34

Safety Statements 

26-27-36/37/39-45

RIDADR 

UN 2987 8/PG 2

WGK Germany 

3

F 

10-21

Hazard Note 

Corrosive/Moisture Sensitive

TSCA 

No

HazardClass 

8

PackingGroup 

II

HS Code 

29319090

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

1H,1H,2H,2H-Perfluorooctyltrichlorosilane Usage And Synthesis

Chemical Properties

colourless liquid

Uses

1H,1H,2H,2H-Perfluorooctyltrichlorosilane is used in the silanization of silicon wafer. Self assembled monolayers treated with this, acts as an anti adhesive layer and release of cured poly(dimethyl siloxanes). It is also used to fabricate chemical surface patterns of self assembled monolayers.

General Description

Trichloro(1H,1H,2H,2H-perfluorooctyl)silane (PFOCTS) is a chlorosilane that forms a self-assembled monolayer (SAM) on a variety of substrates. It is majorly used to modify the surface with superhydrophobic properties. It is a biocompatible polymer with low surface energy. PFOCTS exhibits anti-fouling properties with high wettability which facilitates the release of different composites from the mold.

Flammability and Explosibility

Not classified

Synthesis

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctene, starting materials, are charged under an N2 atmosphere to a three-necked glass flask, and CPC 072 (Pt(0)-divinyltetramethyidisiloxane in xylene) is added. Trichlorosilane is added dropwise at room temperature and with stirring over 85 minutes. The immediately ensuing reaction is exothermic, the temperature rising to 115° C. After the purification, 1H,1H,2H,2H-Perfluorooctyltrichlorosilane are obtained (yield: 99%).

1H,1H,2H,2H-Perfluorooctyltrichlorosilane(78560-45-9)Related Product Information

• 1H,1H,2H,2H-Perfluorooctyltriethoxysilane
• 1H,1H,2H,2H-PERFLUOROOCTYLTRIMETHOXYSILANE
• 1H,1H,2H,2H-Perfluorodecyltrimethoxysilane
• 1H,1H,2H,2H-Perfluorodecyltriethoxysilane
• 1H,1H,2H,2H-Perfluorodecyltrichlorosilane
• HEXYLTRICHLOROSILANE
• Octyltrichlorosilane
• Amyltrichlorosilane (mixed isomers)(Pentyltrichlorosilane)
• N-BUTYLTRICHLOROSILANE
• Methyltrichlorosilane
• 1H,1H,2H,2H-Perfluorooctyltrichlorosilane
• Ethyltrichlorosilane
• 3-CYANOPROPYLMETHYLDICHLOROSILANE
• Trichlorosilane
• OCTYL DICHLOROSILANE
• (TRIDECAFLUORO-1,1,2,2-TETRAHYDROOCTYL)SILANE
• N-HEPTYLTRICHLOROSILANE
• HEXYLDICHLOROSILANE