Monoperoxyphthalic acid magnesium salt hexahydrate Chemical Properties

Melting point:

93 °C (dec.)(lit.)

storage temp. 

Sealed in dry,Room Temperature

solubility 

DMSO, Methanol

form 

Solid

color 

White to Off-White

InChI

InChI=1S/2C8H6O5.Mg.H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;/h2*1-4,12H,(H,9,10);;1H2/q;;+2;/p-3

InChIKey

WWOYCMCZTZTIGU-UHFFFAOYSA-L

SMILES

C(C1C=CC=CC=1C1O[O-][Mg+2]2([O-]OC(C3C=CC=CC=3C(=O)[O-])=O2)O=1)(=O)[O-].[H+].O

CAS DataBase Reference

84665-66-7(CAS DataBase Reference)

Safety Information

Hazard Codes 

O,Xi

Risk Statements 

8-36/37/38

Safety Statements 

26

WGK Germany 

3

HS Code 

29173990

MSDS

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Monoperoxyphthalic acid magnesium salt hexahydrate Usage And Synthesis

Chemical Properties

White Granules

Uses

Reagent for:

• Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
• Oxidation rections under mild conditions
• Epoxidation of unsaturated steroids
• Synthesis of ring-B oxygenated steroids as anticancer agents

Uses

Monoperoxyphthalic acid magnesium salt hexahydrate is used as disinfectant for hard surfaces (hospital, food industrial, institution).

General Description

Magnesium monoperoxyphthalate hexahydrate is an organic peroxide used in many oxidation reactions. It exhibits non-deflagrating and non-shock-sensitive properties and also used as a surface disinfectant.

reaction suitability

reagent type: oxidant

Purification Methods

MMPP is a safer reagent than m-chloroperbenzoic acid for oxidation reactions because it is not as explosive and has advantages of solubility. It is soluble in H2O, low-molecular-weight alcohols, i-PrOH and DMF. The product of reaction, Mg phthalate, is soluble in H2O. It has been used in aqueous phase to oxidise compounds in e.g. CHCl3 and using a phase transfer catalyst, e.g. methyltrioctylammonium chloride [Brougham Synthesis 1015 1987]. The oxidising activity can be checked (as for perbenzoic acid in Silbert et al. Org Synth Coll Vol V 906 1973], and if found to be low it would be best to prepare afresh from phthalic anhydride (1mol), H2O2 (1mol) and MgO at 20-25o to give MMPP. [Hignett, European Pat Appl 27 693 1981, Chem Abstr 95 168810 1981, Beilstein 9 IV 3260.]

Monoperoxyphthalic acid magnesium salt hexahydrate(84665-66-7)Related Product Information

• ethyl hydroperoxide
• MAGNESIUM BENZOATE
• MAGNESIUM FORMATE DIHYDRATE
• MONOPEROXYPHTHALIC ACID MAGNESIUM SALT, HEXAHYDRATE
• Perbenzoic acid
• Peroxyacetic acid
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• MAGNESIUM METHOXIDE
• Magnesium ethoxide
• Hydrogen peroxide
• Potassium hydrogen phthalate
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• Monoperoxyphthalic acid magnesium salt hexahydrate
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• MAGNESIUM MONOPEROXYPHTHALATE HEXAHYDRAT E, TECH., 80%
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