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Tin(II) fluoride

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Tin(II) fluoride Basic information

Product Name:
Tin(II) fluoride
Synonyms:
  • STANNOUS FLUORIDE
  • TIN(+2)FLUORIDE
  • TIN(II) FLUORIDE
  • Tin difluoride
  • TIN FLUORIDE
  • cap-tinmouthrinse
  • crest
  • Tin(II) fluoride anhydrous
CAS:
7783-47-3
MF:
F2Sn
MW:
156.71
EINECS:
231-999-3
Product Categories:
  • Inorganics
  • metal halide
Mol File:
7783-47-3.mol
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Tin(II) fluoride Chemical Properties

Melting point:
215°C
Boiling point:
850°C
Density 
4.57 g/mL at 25 °C (lit.)
storage temp. 
-20°C
solubility 
soluble in H2O; insoluble in ethanol, ethyl ether,chloroform
form 
Powder, Crystals or Crystalline Powder
Specific Gravity
4.57
color 
White to off-white
Water Solubility 
Soluble in potassium hydroxide and potassium fluoride. Insoluble in water, ethanol, ether and chloroform.
Sensitive 
Air & Moisture Sensitive
Merck 
14,8784
Exposure limits
ACGIH: TWA 2 mg/m3; TWA 2.5 mg/m3
NIOSH: IDLH 100 mg/m3; IDLH 250 mg/m3; TWA 2 mg/m3
Stability:
Stable. Non-flammable. Avoid contact with water or oxidizing agents. Moisture-sensitive.
InChIKey
ANOBYBYXJXCGBS-UHFFFAOYSA-L
LogP
-1.357 (est)
CAS DataBase Reference
7783-47-3(CAS DataBase Reference)
NIST Chemistry Reference
Tin difluoride(7783-47-3)
EPA Substance Registry System
Tin fluoride (SnF2) (7783-47-3)
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Safety Information

Hazard Codes 
Xn,C
Risk Statements 
22-38-41
Safety Statements 
26-39
RIDADR 
UN 2923 8/PG 3
WGK Germany 
3
RTECS 
XQ3450000
1-3-10
Hazard Note 
Corrosive
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
28261990
Hazardous Substances Data
7783-47-3(Hazardous Substances Data)

MSDS

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Tin(II) fluoride Usage And Synthesis

Chemical Properties

white crystals or powder

Chemical Properties

Stannous fluoride is a white crystalline solid with a bitter, salty taste.

Uses

Stannous fluoride (SnF2) is used as a toothpaste additive to help prevent tooth decay.

Uses

Tin(II) fluoride is used in the prevention of dental caries. It is an active ingredient in toothpastes.

Uses

Dental caries prophylactic.

Definition

ChEBI: Stannous fluoride is an inorganic fluoride salt.

General Description

White crystalline solid. Sinks and mixes with water.

Air & Water Reactions

Water soluble.

Reactivity Profile

Tin(II) fluoride, a strong reducing agent, is incompatible with oxidizers. Avoid contact with acids - HF fumes may be produced [USCG, 1999].

Hazard

Toxic by ingestion, strong irritant to skin and tissue.

Health Hazard

EYES: Severe irritation - corrosive, irreversible. SKIN: Corrosive on abraded skin, no effect on intact skin.

Flammability and Explosibility

Not classified

Safety Profile

Poison by ingestion and intraperitoneal routes. Questionable carcinogen. Mutation data reported. When heated to decomposition it emits toxic fumes of F-. See also TIN COMPOUNDS.

Potential Exposure

Stannous fluoride is used in dental caries (tooth decay); as an ingredient of cavity-preventing toothpastes.

Shipping

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2923 Corrosive solids, toxic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, 6.1Poisonous material, Technical Name Required

Incompatibilities

A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Reacts with acids, forming hydrogen fluoride fumes. Reacts violently with chlorine and metal nitrates. Reacts with metals releasing flammable hydrogen gas.

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