(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE CAS#: 185449-86-9

ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE

Basic information Description Safety Supplier Related

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Basic information

Product Name:

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE

Synonyms:

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE
(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a
3,4-a']dinaphthalen-4-yl)dimethylamine,min.98%
3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%
N,N,2,6-Tetramethyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(11bS)-N,N,2,6-tetraMethyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine
3,4-a']dinaphthalen-4-yl)dimethylamine,98%
(11bS)-N,N,2,6-Tetramethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine,99%e.e.

CAS:

185449-86-9

MF:

C24H22NO2P

MW:

387.41

Product Categories:

Chiral Phosphine
CPN

Mol File:

185449-86-9.mol

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(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Chemical Properties

Melting point:: 228-229°C
Boiling point:: 571.0±53.0 °C(Predicted)
alpha: +636° (c 0.30, CH2Cl2)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
pka: 1.32±0.20(Predicted)
color: off-white
Sensitive: moisture sensitive
InChI: 1S/C24H22NO2P/c1-15-13-17-9-5-7-11-19(17)21-22-20-12-8-6-10-18(20)14-16(2)24(22)27-28(25(3)4)26-23(15)21/h5-14H,1-4H3
InChIKey: MXASPZVRFOFONU-UHFFFAOYSA-N
SMILES: CN(C)P1Oc2c(C)cc3ccccc3c2-c4c(O1)c(C)cc5ccccc45

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Safety Information

Hazard Codes: Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-36/37/39
WGK Germany: WGK 3
Storage Class: 11 - Combustible Solids
Hazard Classifications: Acute Tox. 4 Oral

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(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE Usage And Synthesis

Description

1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.
2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
3. Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
4. Ligand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes.
5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.

(S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINESupplier

J & K SCIENTIFIC LTD.

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Meryer (Shanghai) Chemical Technology Co., Ltd.

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Daicel Chiral Technologies (China)CO.,LTD

Tel: 021-50460086-9 15921403865
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Tianjin Derchemist Science & Technology Co., Ltd.

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Shanghai Incat Chemtech Co.,Ltd.

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