5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE
5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE Basic information
- Product Name:
- 5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE
- Synonyms:
-
- 2,7,12,17-tetrakis(pyridin-4-yl)-21,22,23,24-tetraazapentacyclo[16.2.1.1^{3,6}.1^{8,11}.1^{13,16}]tetracosa-1,3,5,7,9,11,13,15,17,19-decaene
- 5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphine 97%
- COTPYP
- 4-PYP
- 5,10,15,20-tetrapyridin-4-yl-21,22-dihydroporphyrin
- 5,10,15,20-Tetra(4-pyridyl)
- 23h-porphine,5,10,15,20-tetra-4-pyridinyl-21
- MESO-TETRA(4-PYRIDYL)PORPHINE
- CAS:
- 16834-13-2
- MF:
- C40H26N8
- MW:
- 618.69
- EINECS:
- 240-858-5
- Product Categories:
-
- organic building block
- Standards and Kits
- Biochemistry
- Synthetic Porphyrins
- porphine (porphyrin) ligand
- Analytical Chemistry
- Chelating Reagents
- Porphines
- Porphyrin Building Blocks
- Porphyrins
- Natural Porphyrins and Derivitives
- Organics
- Mol File:
- 16834-13-2.mol
5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE Chemical Properties
- Density
- 1.335±0.06 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Powder
- color
- purple
- λmax
- 442 nm
- BRN
- 635257
- InChIKey
- DNZSHSJERXNJGX-XXDGMDECSA-N
- SMILES
- C1(C2C=CN=CC=2)=C2N=C(C(C3C=CN=CC=3)=C3NC(=C(C4C=CN=CC=4)C4=NC(=C(C5C=CN=CC=5)C5NC1=CC=5)C=C4)C=C3)C=C2 |c:18,t:7,21,32|
- EPA Substance Registry System
- 21H,23H-Porphine, 5,10,15,20-tetra-4-pyridinyl- (16834-13-2)
MSDS
- Language:English Provider:SigmaAldrich
5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE Usage And Synthesis
Description
5,10,15,20-(tetra-4-pyridyl)porphyrin is a pyridine substituted synthetic porphyrin. It can act as a sensitive amperometric sensor.
Chemical Properties
Purple to dark purple solid
Uses
5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphine is used in the making of coordination catalysts.
General Description
5,10,15,20-tetra-4-pyridyl-21H,23H-porphine (H2TPyP)?can react with [Re6(μ3-Se)8(Pet3)5(NCMe]2+ and 2,4,6-tri-4-pyridyl-1,3,5-triazine to form tri- and tetra complexes. 1 Trace amounts of nitroaromatic explosives can be detected by porphyrin functionalized graphene. It behaves as a sensitive amperometric sensor. 2
Purification Methods
Purify it by chromatography on alumina (neutral, Grade I), with CHCl3/MeOH (80:20) followed by recrystallisation from CH2Cl2/MeOH [Yamashita et al. J Phys Chem 91 3055 1987]. [Kalyanasundaram Inorg Chem 23 2453 1984, Okuno et al. Synthesis 537 1980.]
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5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE(16834-13-2)Related Product Information
- meso-Tetra (p-bromophenyl) porphine
- 5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE
- 5,10,15,20-TETRAKIS(4-FLUOROPHENYL)-21H,23H-PORPHINE)
- 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE
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- 3-PYRIDIN-4-YLANILINE
- 2-Acetylpyridine
- meso-Tetra(4-carboxyphenyl)porphine
- TPP
- ZINC PORPHYRIN DIMER
- 5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE
- 5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE
- 5,10,15,20-tetra(3-hydroxyphenyl)porphyrin
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- TMPYP
- 5,10,15,20-TETRA(4-PYRIDYL)-21H,23H-PORPHINE