ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic rhodium > Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Basic information
- Product Name:
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- Synonyms:
-
- Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,98% [Rh(COD)2]BF4
- Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate
- Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate
- ooctadiene)rhodium(Ⅰ)tetrafL
- (1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate
- RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX
- Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis
- BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE
- CAS:
- 35138-22-8
- MF:
- C16H24BF4Rh
- MW:
- 406.07
- EINECS:
- 460-220-1
- Product Categories:
-
- Rh
- organometallic complex
- Mol File:
- 35138-22-8.mol
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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties
- Melting point:
- 210 °C
- Density
- 0.42 g/cm3 (20℃)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Powder
- color
- Red
- PH
- 7 (5g/l, H2O, 20℃)
- Water Solubility
- insoluble
- Sensitive
- Slightly air & moisture sensitive
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 - InChIKey
- IEMMJJILGGBYNZ-GSLAGHMSSA-M
- CAS DataBase Reference
- 35138-22-8(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- F,Xi
- Risk Statements
- 11-34
- Safety Statements
- 16-45-36/37/39-26
- RIDADR
- UN 2921
- WGK Germany
- 2
- Hazard Note
- Irritant
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 28439000
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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Usage And Synthesis
Uses
- Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
- Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions.
Chemical Properties
dark red
Uses
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials
Raw materials
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborateSupplier
Shanghai Incat Chemtech Co.,Ltd. Gold
- Tel
- 021-57603038 13601791340
- 307593986@qq.com
Shaanxi Rock New Materials Co., Ltd. Gold
- Tel
- 0917-8888777, 3380777,18691786767; 15619786767
- xuya@bjrock.com
NANJING YIHUA BIOTECHNOLOGY Co., Ltd Gold
- Tel
- 15171470753
- 3105244229@qq.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate(35138-22-8)Related Product Information
- Sodium tetrafluoroborate
- Octamethylcyclotetrasiloxane
- Rhodium
- 1,3-CYCLOOCTADIENE
- 1,5-Cyclooctadiene
- Potassium tetrafluoroborate
- Fluoroboric acid
- Ammonium fluoborate
- Dichloro(1,5-cyclooctadiene)palladium(II)
- methoxy(cyclooctadiene)rhodium(i) dimer
- Chloro(1,5-cyclooctadiene)iridium(I) dimer
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
- Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
- BIS(1 5-CYCLOOCTADIENE)RHODIUM(I)
- Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium
- Tris(dibenzylideneacetone)dipalladium
- Dichloro(1,5-cyclooctadien)ruthenium(II) polymer
- BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE