Ethyl phenylacetate Chemical Properties

Melting point:

-29 °C

Boiling point:

229 °C(lit.)

Density 

1.03 g/mL at 25 °C(lit.)

vapor pressure 

22.7Pa at 20℃

refractive index 

n20/D 1.497(lit.)

FEMA 

2452 | ETHYL PHENYLACETATE

Flash point:

172 °F

storage temp. 

Store below +30°C.

solubility 

Chloroform (Slightly), Ethyl Acetate (Slightly)

color 

Colourless

Odor

at 10.00 % in dipropylene glycol. sweet floral honey rose balsam cocoa

Odor Type

floral

Water Solubility 

insoluble

JECFA Number

1009

Merck 

14,3840

BRN 

509140

Dielectric constant

5.4（21℃）

InChIKey

DULCUDSUACXJJC-UHFFFAOYSA-N

LogP

2.36 at 22℃

CAS DataBase Reference

101-97-3(CAS DataBase Reference)

NIST Chemistry Reference

Benzeneacetic acid, ethyl ester(101-97-3)

EPA Substance Registry System

Benzeneacetic acid, ethyl ester (101-97-3)

Safety Information

Safety Statements 

23-24/25

WGK Germany 

2

RTECS 

AJ2824000

TSCA 

Yes

HS Code 

29163500

Hazardous Substances Data

101-97-3(Hazardous Substances Data)

Toxicity

The acute oral LD₅₀ value in rats was reported as 3.30g/kg(2.52-4.08 g/kg) (Moreno,1973).The acute dermal LD₅₀ in rabbits was reported as > 5g/kg(Moreno, 1973).

MSDS

• Language:English Provider:Phenylacetic acid ethyl ester
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Ethyl phenylacetate Usage And Synthesis

Chemical Properties

Ethyl Phenylacetate is a volatile aroma component of fruit and honey. It is a clear colourless to pale yellowish liquid with a pleasant, strong, sweet odor reminiscent of honey and a bittersweet flavor. Small amounts are used in flower perfumes and in fruit flavors.

Occurrence

Reported found in grapefruit juice, apple juice, figs, guava, pineapple, papaya, cognac, cider, grape wines and port wine.

Uses

Ethyl phenylacetate was used to study the solvent-based self-healing of epoxy materials. It is also used as a flavoring agent, flavor animal feeds, In perfumery.

Definition

ChEBI: Ethyl phenylacetate is a member of benzenes. It is a less toxic, greener solvent. It is non-mutagenic.

Preparation

Ethyl phenylacetate is prepared by heating at the boil phenylacetonitrile and sulfuric acid in alcohol solution; by esterification of the acid catalyzed by HCl or H2SO4.

Aroma threshold values

Detection: 650 ppb

Taste threshold values

Taste characteristics at 10 ppm: sweet, fruity, honey, cocoa, apple and woody

General Description

Ethyl phenylacetate is a less toxic, greener solvent. It is non-mutagenic.

Flammability and Explosibility

Non flammable

Biochem/physiol Actions

Taste at 5 to 10 ppm

Safety Profile

Moderately toxic by ingestion. Combustible liquid. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

Purification Methods

Shake the ester with saturated aqueous Na2CO3 (three times), aqueous 50% CaCl2 (twice) and saturated aqueous NaCl (twice). Dry with CaCl2 and distil it under reduced pressure. [Beilstein 9 H 434, 9 IV 1618.]

Ethyl phenylacetate(101-97-3)Related Product Information

• ETHYL P-TOLYLACETATE
• 2,2-DIMETHYL-5-PHENYL-1,3-DIOXANE-4,6-DIONE
• Diethyl phenylmalonate
• ETHYL HOMOVANILLATE
• Homatropine Hydrobromide
• BENACTYZINE HYDROCHLORIDE
• 2,3-DIPHENYLMALEIC ANHYDRIDE
• ETHYL PHENYLCYANOACETATE
• 2-PHENYLGLUTARIC ANHYDRIDE
• Scopolamine hydrobromide
• Ethyl phenylacetate
• ETHYL O-TOLYLACETATE
• ALPHA,ALPHA-DIPHENYL-GAMMA-BUTYROLACTONE
• 2-Oxo-2-phenylacetic acid ethyl ester
• O,O-Dimethyl-S-(phenylacetic acid ethyl ester) phosphorodithioate
• Ethyl 4-bromophenylacetate
• (R)-2-Hydroxy-2-phenylacetic acid ethyl ester,(2R)-2-Hydroxy-2-phenylacetic acid ethyl ester
• Ethyl 4-hydroxyphenylacetate