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DL-CAMPHORQUINONE

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DL-CAMPHORQUINONE Basic information

Product Name:
DL-CAMPHORQUINONE
Synonyms:
  • DL-CAMPHORQUINONE FOR SYNTHESIS
  • (±)-camphandione
  • 3-dione,1,7,7-trimethyl-,(+-)-Bicyclo[2.2.1]heptane-2
  • 4,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione
  • 7,7-trimethyl-3-dion(+/-)-bicyclo[2.2.1]heptane-1
  • Bicyclo[2.2.1]heptane-2,3-dione, 1,7,7-trimethyl-, (.+/-.)-
  • bicyclo[2.2.1]heptane-2,3-dione,1,7,7-trimethyl-
  • camphoquinone
CAS:
10373-78-1
MF:
C10H14O2
MW:
166.22
EINECS:
233-814-1
Product Categories:
  • Bicyclic Monoterpenes
  • Biochemistry
  • Functional Materials
  • Photopolymerization Initiators
  • Terpenes
  • Building Blocks/Intermediates
Mol File:
10373-78-1.mol
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DL-CAMPHORQUINONE Chemical Properties

Melting point:
197-203 °C (lit.)
Boiling point:
234.44°C (rough estimate)
alpha 
-5~+5°(20℃/D)(c=2, CHCl3)
Density 
0.9817 (rough estimate)
refractive index 
1.4859 (estimate)
storage temp. 
Store below +30°C.
solubility 
Soluble in ethanol, ethyl ether and benzene.
form 
Fine Crystalline Powder
color 
Yellow
BRN 
1909463
InChI
InChI=1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3
InChIKey
VNQXSTWCDUXYEZ-UHFFFAOYSA-N
SMILES
C12(C)C(C)(C)C(CC1)C(=O)C2=O
LogP
1.470 (est)
CAS DataBase Reference
10373-78-1(CAS DataBase Reference)
EPA Substance Registry System
Bicyclo[2.2.1]heptane-2,3-dione, 1,7,7-trimethyl- (10373-78-1)
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Safety Information

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
22-24/25-36-26
WGK Germany 
3
TSCA 
Yes
HS Code 
2914 29 00

MSDS

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DL-CAMPHORQUINONE Usage And Synthesis

Chemical Properties

YELLOW FINE CRYSTALLINE POWDER

Uses

initiator for visible-light-cured dental acrylic-composite materials.

Uses

Camphorquinone derivative (i.e. carboxylated camphorquinone) is used as visible-light photoinitiator in biomedical applications. It is also used in dentistry and is often used in conjunction with hydrogen donating amine.

Uses

CQ-amines are used as a photo initiators for free radical polymerization. CQ was used as an initiator in the preparation of silver nanoparticle/silica/ polymer nanocomposites. Photopolymerization kinetics of dimethacrylates were studied using the CQ/amine initiator system.

Definition

ChEBI: Bornane-2,3-dione is a bornane monoterpenoid that is bicyclo[2.2.1]heptane substituted by methyl groups at positions 1, 7 and 7 and oxo groups at positions 2 and 3. It is a bornane monoterpenoid and a carbobicyclic compound.

General Description

Camphorquinone (CQ) absorbs UV radiation in the region of 200-300nm due to the Π?Π* transition and visible light (400-500nm) due to the n, Π* transition of the α-dicarbonyl chromophore.

Purification Methods

Purification is the same as for above enantiomers. [Huckel & Fichtig Justus Liebigs Ann Chem 628 81 1962, Evans et al. J Chem Soc 137 1939, Beilstein 7 I 325.]

DL-CAMPHORQUINONESupplier

Hubei Hongxin Ruiyu Fine Chemical Co., Ltd. Gold
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