ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organomagnesium > TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Basic information
- Product Name:
- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
- Synonyms:
-
- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
- (trimethylsilyl)methylmagnesium chl. sol
- Trimethylsilylmethylmagnesium chloride (20% in ethyl ether
- (TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER
- (TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER
- [(Trimethylsilyl)methyl]magnesium Chloride 1.0 M In Diethyl Ether
- [(Trimethylsilyl)methyl]magnesium Chloride, 1.0 M In Tetrahydrofuran
- (Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF
- CAS:
- 13170-43-9
- MF:
- C4H11ClMgSi
- MW:
- 146.97
- Product Categories:
-
- Si (Classes of Silicon Compounds)
- Si-(C)4 Compounds
- Silicon Compounds (for Synthesis)
- Synthetic Organic Chemistry
- Typical Metal Compounds
- Alkyl
- Classes of Metal Compounds
- Grignard Reagents
- Grignard Reagents & Alkyl Metals
- Mg (Magnesium) Compounds
- Grignard Reagents
- Organometallic Reagents
- Mol File:
- 13170-43-9.mol
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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Chemical Properties
- Melting point:
- 105.8-106.4 °C
- Density
- 1.04
- Flash point:
- -40°C
- storage temp.
- Flammables + water-Freezer (-20°C)e area
- solubility
- Sol ethereal solvents; reacts with protic solvents.
- form
- Low Melting Solid
- Specific Gravity
- 0.912
- color
- Clear colorless to yellow to greenish
- Sensitive
- Air & Moisture Sensitive
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- BRN
- 3587255
- CAS DataBase Reference
- 13170-43-9(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- F+,C,F
- Risk Statements
- 12-14-22-34-66-67-19-11
- Safety Statements
- 16-26-36/37/39-43-45
- RIDADR
- UN 3399 4.3/PG 1
- WGK Germany
- 1
- F
- 10
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29319090
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Usage And Synthesis
Chemical Properties
Grey liquid
Uses
Trimethylsilylmethylmagnesium Chloride is used in the methylenation of carbonyl compounds; provides a variety of methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in the Presence of Cobalt Catalysts etc.
Uses
Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.
Preparation
From (chloromethyl)trimethylsilane and magnesium in an ethereal solvent.
reaction suitability
reaction type: Grignard Reaction
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDESupplier
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
Beijing Donghualituo Techonlogy Development Co.,Ltd.
- Tel
- 010-88425576
- sales@dhltchem.com
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
TCI (Shanghai) Development Co., Ltd.
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE(13170-43-9)Related Product Information
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- 3,4,5-TRIMETHOXYPHENYLMAGNESIUM BROMIDE SOLUTION 0.5M IN TETRAHYDROFURAN
- 3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE
- Lithium diisopropylamide
- 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
- 2-METHOXYBENZYLMAGNESIUM CHLORIDE
- 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE
- 2-NAPHTHYLMAGNESIUM BROMIDE
- CYCLOPENTYLMAGNESIUM BROMIDE
- M-TOLYLMAGNESIUM CHLORIDE
- Zinc chloride
- Methylmagnesium Bromide
- TRIMETHYLSILANE
- Magnesium chloride
- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
- Methylmagnesium chloride
- DIMETHYLETHYLSILYLMETHYLMAGNESIUM CHLORIDE