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6-Benzylaminopurine

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6-Benzylaminopurine Basic information

Product Name:
6-Benzylaminopurine
Synonyms:
  • 6-BENZYLAMINOPURINERESEARCH GRADE
  • 6-Benzylaminopurine,BA, N6-Benzyladenine
  • 6-BenzylaMinopurine, 99% 5GR
  • 6-Benzyil AMinopurine
  • 6-benzyl-6H-purin-6-aMine
  • 6-BenzylaMino Purine Tech
  • 6-(Benzylamino)-9H-purine
  • N-Benzyl-9H-purin-6-amine, N-(9H-Purin-6-yl)benzylamine
CAS:
1214-39-7
MF:
C12H11N5
MW:
225.25
EINECS:
214-927-5
Product Categories:
  • Biochemistry
  • Cytokinins
  • Nucleobases and their analogs
  • Nucleosides, Nucleotides & Related Reagents
  • Plant Growth Regulators
  • Plant Hormones
  • Pharmaceutical Raw Materials
  • Miscellaneous
  • Purine
  • Amines
  • PLANT GROWTH REGULATOR
  • plantgrowth
Mol File:
1214-39-7.mol
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6-Benzylaminopurine Chemical Properties

Melting point:
230-233 °C
Boiling point:
145 °C(lit.)
Density 
0.899 g/mL at 20 °C
vapor density 
>1 (vs air)
vapor pressure 
3.3 mm Hg ( 20 °C)
refractive index 
n20/D 1.418(lit.)
Flash point:
103 °F
storage temp. 
2-8°C
solubility 
H2O: soluble
pka
9.36±0.20(Predicted)
form 
Liquid
color 
White to very faint yellow
Odor
Characteristic acrylic.
Water Solubility 
Soluble in water, methanol and acetone. Slightly soluble in ethyl acetate and dichloromethane and toluene. Insoluble in n-hexane.
BRN 
19406
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
NWBJYWHLCVSVIJ-UHFFFAOYSA-N
CAS DataBase Reference
1214-39-7(CAS DataBase Reference)
NIST Chemistry Reference
1H-purin-6-amine, n-(phenylmethyl)-(1214-39-7)
EPA Substance Registry System
N-Benzyladenine (1214-39-7)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22-22
Safety Statements 
9-24/25-37/39-26-36-23
RIDADR 
UN 2348 3/PG 3
WGK Germany 
3
RTECS 
UD3150000
8
TSCA 
Yes
HS Code 
29335995
Hazardous Substances Data
1214-39-7(Hazardous Substances Data)
Toxicity
LD50 orl-rat: 2125 mg/kg TOIZAG 19,336,72

MSDS

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6-Benzylaminopurine Usage And Synthesis

Chemical Properties

white to light yellow crystal powder

Chemical Properties

Colorless to off-white or yellow powder. Corrosive.

Uses

6-Benzylaminopurine can be used as inhibitor of respiratory kinase in plants.

Uses

6-Benzylaminopurine is a plant growth regulator that belongs to the class of first generation synthetic cytokinin used in agriculture.
6-Benzylaminopurine has been used:
to induce sprouting in plant materials.
in seed germination medium for culturing of seeds.
to modify Murashige and Skoog (MS) media for shoot initiation.
6-Benzylaminopurine, benzyl adenine (BAP) is a synthetic cytokinin which together with auxins elicits plant growth and development responses. BAP is a widely use cytokinin supplement to plant growth media such as Murashige and Skoog medium, Gamborg’s medium, and Chu’s N6 medium.

Definition

ChEBI: A member of the class of 6-aminopurines that is adenine in which one of the hydrogens of the amino group is replaced by a benzyl group.

Health Hazard

Recommended Personal Protective Equipment: Self-contained breathing apparatus, rubber gloves, acid goggles; Symptoms Following Exposure: Vapor is irritating when breathed at high concentrations. Contact with liquid causes irritation of skin and burning of eyes; General Treatment for Exposure: INHALATION: remove to fresh air; administer artificial respiration or oxygen if indicated; call a physician. SKIN AND EYES: wash with plenty of water; Toxicity by Inhalation (Threshold Limit Value): Data not available; Short-Term Exposure Limits: LD50 100 ppm, 4 hr; Toxicity by Ingestion: Grade 2; LD50 = 0.5 to 5 g/kg (rat); Late Toxicity: Data not available; Vapor (Gas) Irritant Characteristics: Vapors cause a slight smarting of the eyes or respiratory system if present in high concentrations. The effect is temporary; Liquid or Solid Irritant Characteristics: Minimum hazard. If spilled on clothing and allowed to remain, may cause smarting and reddening of the skin; Odor Threshold: Data not available.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Polymerizes upon exposure to heat; uncontrolled bulk polymerization can be explosive; Inhibitor of Polymerization: Methyl ether of hydroquinone: 15-100 ppm. Store in contact with air.

Agricultural Uses

Plant growth regulator: A plant growth regulator used to lengthen and enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in EU countries. Registered for use in the U.S.

Trade name

ABG® 3034; ACCEL®; AGTROL®; 6-BA®; BA® (growth stimulant); CHRYSAL BVB®; EXILIS®; PERLAN®; PROMALIN®; SD® 4901; SQ® 4609

Safety Profile

Moderately toxic by ingestion andskin contact. Human mutation data reported. Whenheated to decomposition it emits toxic vapors of NOx.

Potential Exposure

A polyamine plant growth regulator used to lengthen and enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in the EU countries.

Shipping

UN3259 Amines, solid, corrosive, n.o.s, or Polyamines, solid, corrosive, n.o.s., Hazard class: 8; Labels: 8—Corrosive material, Technical Name Required.

Purification Methods

It is purified by recrystallisation from aqueous EtOH. It has at 207 and 270nm (H2O), 268 nm max (pH 6), 274nm (0.1 N HCl) and 275nm (0.1 N NaOH). [Daly J Org Chem 21 1553 1956, Bullock et al. J Am Chem Soc 78 3693 1956, Beilstein 26 III/IV 3575.]

Incompatibilities

May react with strong oxidizers such as chlorates, peroxides, nitrates, etc. May release heat on contact with water. Solid and corrosive amines are chemical bases. Neutralize acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate flammable gaseous hydrogen in combination with strong reducing agents, such as hydrides.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

6-BenzylaminopurineSupplier

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