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ChemicalBook >  Product Catalog >  Flavors and fragrances >  Synthetic fragrances >  Ketones spices >  Terpene ketone >  (E)-1-(2,6,6-TRIMETHYL-CYCLOHEX-2-ENYL)-BUT-2-EN-1-ONE

(E)-1-(2,6,6-TRIMETHYL-CYCLOHEX-2-ENYL)-BUT-2-EN-1-ONE

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(E)-1-(2,6,6-TRIMETHYL-CYCLOHEX-2-ENYL)-BUT-2-EN-1-ONE Basic information

Product Name:
(E)-1-(2,6,6-TRIMETHYL-CYCLOHEX-2-ENYL)-BUT-2-EN-1-ONE
Synonyms:
  • (2E)-1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-2-buten-1-one
  • 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-,(E)-2-Buten-1-one
  • 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-trans-2-Buten-1-one
  • 2-Buten-1-one, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-, (E)-
  • 2-Buten-1-one,1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-,(E)-
  • 6,6-trimethyl-2-cyclohexen-1-yl)-1-((e)-2-buten-1-on
  • trans-2-Buten-1-one, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-
  • (E)-1-(2,6,6-TRIMETHYL-CYCLOHEX-2-ENYL)-BUT-2-EN-1-ONE
CAS:
24720-09-0
MF:
C13H20O
MW:
192.3
EINECS:
246-430-4
Product Categories:
  • ketone Flavor
Mol File:
24720-09-0.mol
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(E)-1-(2,6,6-TRIMETHYL-CYCLOHEX-2-ENYL)-BUT-2-EN-1-ONE Chemical Properties

Boiling point:
267.1±29.0 °C(Predicted)
Density 
0.898±0.06 g/cm3(Predicted)
vapor pressure 
3.2Pa at 25℃
refractive index 
n20/D 1.496
FEMA 
4088 | TRANS-ALPHA-DAMASCONE
Flash point:
100 °C
Odor
at 1.00 % in dipropylene glycol. floral rose apple fruity black currant
Odor Type
fruity
Water Solubility 
140mg/L at 20℃
JECFA Number
2188
LogP
3.66 at 25℃
EPA Substance Registry System
2-Buten-1-one, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-, (2E)- (24720-09-0)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
43
Safety Statements 
36/37
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(E)-1-(2,6,6-TRIMETHYL-CYCLOHEX-2-ENYL)-BUT-2-EN-1-ONE Usage And Synthesis

Chemical Properties

Colorless to pale yellow clear liquid; floral rose, apple fruity, black currant aroma.

Occurrence

Reported found in rose, tea, and tobacco

Definition

ChEBI: 1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enone is an enone with a trimethylcyclohexenyl substituent at C-1. It has a role as a fragrance and an allergen.

Aroma threshold values

High strength odor, fruity type; recommend smelling in a 1.0% solution or less.

Synthesis Reference(s)

The Journal of Organic Chemistry, 55, p. 1106, 1990 DOI: 10.1021/jo00290a057
Tetrahedron Letters, 23, p. 335, 1982 DOI: 10.1016/S0040-4039(00)86824-0

Flammability and Explosibility

Not classified

(E)-1-(2,6,6-TRIMETHYL-CYCLOHEX-2-ENYL)-BUT-2-EN-1-ONESupplier

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