POTASSIUM DIPHENYLPHOSPHIDE Chemical Properties

Density 

0.929 g/mL at 25 °C

Flash point:

−4 °F

form 

liquid

BRN 

4164304

InChI

1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1

InChIKey

FCLYZQXPJKJTDR-UHFFFAOYSA-N

SMILES

[K]P(c1ccccc1)c2ccccc2

Safety Information

Hazard Codes 

F,C

Risk Statements 

11-19-22-34-40-37

Safety Statements 

16-26-33-36/37/39-45

RIDADR 

UN 2924 3/PG 2

WGK Germany 

1

F 

1-8-10-13

Storage Class

3 - Flammable liquids

Hazard Classifications

Acute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3

MSDS

• Language:English Provider:SigmaAldrich

POTASSIUM DIPHENYLPHOSPHIDE Usage And Synthesis

Uses

• Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009).


• Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007).


• Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004).

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

POTASSIUM DIPHENYLPHOSPHIDE(15475-27-1)Related Product Information

• Diphenylphosphinic acid
• Potassium phosphate tribasic
• POTASSIUM DIPHENYLPHOSPHIDE
• PHOSPHATE STANDARD