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2-Bromoanisole

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2-Bromoanisole Basic information

Product Name:
2-Bromoanisole
Synonyms:
  • 1-bromo-2-methoxy-benzen
  • 2-Bromo-1-methoxybenzene
  • 2-Methoxybromobenzene
  • 2-Methoxyphenyl bromide
  • 2-methoxyphenylbromide
  • 1-BROMO-2-METHOXYBENZENE
  • O-Bromoanisoles
  • 2-BROMOANISOLE, STAB.
CAS:
578-57-4
MF:
C7H7BrO
MW:
187.03
EINECS:
209-425-8
Product Categories:
  • alkyl bromide
  • Aromatic Halides (substituted)
  • Anisole
  • Miscellaneous
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Bromine Compounds
Mol File:
578-57-4.mol
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2-Bromoanisole Chemical Properties

Melting point:
2 °C (lit.)
Boiling point:
223 °C (lit.)
Density 
1.502 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.573(lit.)
Flash point:
206 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Soluble in ethanol and diethyl ether.
form 
Liquid
Specific Gravity
1.502
color 
Clear colorless to slightly yellow
BRN 
1859996
Dielectric constant
8.9600000000000009
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference
578-57-4(CAS DataBase Reference)
NIST Chemistry Reference
1-Bromo-2-methoxybenzene(578-57-4)
EPA Substance Registry System
Benzene, 1-bromo-2-methoxy- (578-57-4)
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Safety Information

Hazard Codes 
N,Xi
Risk Statements 
51/53
Safety Statements 
61-24/25
RIDADR 
UN 3082 9/PG 3
WGK Germany 
2
RTECS 
BZ8500000
8-10-23
TSCA 
T
HS Code 
29093038

MSDS

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2-Bromoanisole Usage And Synthesis

Chemical Properties

colourless liquid

Uses

2-Bromoanisole was used in the synthesis of unsymmetrical substituted biphenyl compounds, used to produce (2-methoxy-phenyl)-acetone at the temperature of 100°C.

Uses

2-Bromoanisole was used in the synthesis of unsymmetrically substituted biphenyl compounds. It was also used in the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3).

General Description

Diffusion coefficients of 2-bromoanisole at infinite dilution in supercritical carbon dioxide has been evaluated by Taylor-Aris chromatographic technique.

Purification Methods

Crystallise the anisole by repeated partial freezing, then distil it under reduced pressure. [Beilstein 6 IV 1037.]

2-Bromoanisole Preparation Products And Raw materials

Raw materials

Preparation Products

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