TERT-BUTYL 4-BROMOBENZYLCARBAMATE
TERT-BUTYL 4-BROMOBENZYLCARBAMATE Basic information
- Product Name:
- TERT-BUTYL 4-BROMOBENZYLCARBAMATE
- Synonyms:
-
- TERT-BUTYL 4-BROMOBENZYLCARBAMATE
- tert-Butyl 4-bromobenzylcarbamate 98%
- Carbamic acid, (4-bromophenyl)methyl-, 1,1-dimethylethyl ester
- (4-BROMO-BENZYL)-CARBAMIC ACID TERT-BUTYL ESTER
- N-BOC-4-broMobenzylaMine
- 4-Bromo-N-BOC-benzylamine
- N-(4-Bromobenzyl)carbamic acid tert-butyl ester
- tert-Butyl N-(4-bromobenzyl)carbamate
- CAS:
- 68819-84-1
- MF:
- C12H16BrNO2
- MW:
- 286.16
- Product Categories:
-
- amine|alkyl bromide| carboxylic ester
- Mol File:
- 68819-84-1.mol
TERT-BUTYL 4-BROMOBENZYLCARBAMATE Chemical Properties
- Melting point:
- 86-88℃
- Boiling point:
- 374.3±25.0 °C(Predicted)
- Density
- 1.319±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- solid
- pka
- 12.05±0.46(Predicted)
- color
- Off-white
TERT-BUTYL 4-BROMOBENZYLCARBAMATE Usage And Synthesis
Synthesis
Tert-Butyl 4-bromobenzylcarbamate is prepared by the reaction of di-tert-butyl dicarbonate and 4-bromobenzylamine hydrochloride. The specific synthesis steps are as follows:
To a stirred suspension of 4-bromo-benzylamine hydrochloride (968mg, 4.35mmol) and triethylamine (0.666ml, 4.79mmol) in chloroform (15ml) was added di-tert-butyldicarbonate (949mg, 4.35mmol). The resulting solution was stirred at ambient temperature for 2h and then diluted with DCM (40ml). The organic solution was washed sequentially with 10% aqueous citric acid (40ml) and brine (40ml). The organic phase was dried over anhydrous magnesium sulfate and the filtrate evaporated at reduced pressure to afford Tert-Butyl 4-bromobenzylcarbamate (1.23g, 99%). 1H NMR 7.48-7.43 (2H, m), 7.18 (2H, d, 8.4), 4.84 (1H, br s), 4.27 (2H, d, 5.7), 1.46 (9H, s).
TERT-BUTYL 4-BROMOBENZYLCARBAMATESupplier
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TERT-BUTYL 4-BROMOBENZYLCARBAMATE(68819-84-1)Related Product Information
- N-Boc-4-(Cyclopropylmethyl)piperazine
- 1-BOC-4-(1-PYRROLIDINYL)-3,6-DIHYDRO-2H-PYRIDINE
- 2(1H)-ISOQUINOLINECARBOXYLIC ACID, 3,4-DIHYDRO-7-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-, 1,1-DIMETHYLETHYL ESTER
- tert-butyl 4-(2-bromo-5-fluoropyridin-4-yl)-4-hydroxypiperidine-1-carboxylate
- 1-N-Boc-4-(Phenylamino)piperidine
- tert-butyl 4-(2-aminoethyl)-3,3-difluoropiperidine-1-carboxylate
- 4-(3-AMINO-PHENYL)-PIPERIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER
- 1-Boc-4-(2-hydroxyethyl)piperidine
- tert-butyl 4-(3-cyano-4-(methoxycarbonyl)phenyl)piperazine-1-carboxylate
- tert-butyl 5-tert-butylisoxazol-3-ylcarbamate
- 1-Piperazinecarboxylic acid, 4-[3-bromo-4-(methoxycarbonyl)phenyl]-, 1,1-dimethylethyl ester
- 5H-Pyrrolo[3,2-c]pyridine-5-carboxylic acid, 1,4,6,7-tetrahydro-4-oxo-2-(4-pyridinyl)-, 1,1-dimethylethyl ester
- INDEX NAME NOT YET ASSIGNED
- Pentanoic acid, 4,5-diamino-5-oxo-, 1,1-dimethylethyl ester
- Boc-4-Bromo-L-beta-phenylalanine
- Boc-4-Bromo-D-beta-phenylalanine
- (4-Bromophenyl)-tert-butoxycarbonylaminoacetic acid methyl ester
- (R,S)-Boc-3-amino-3-(4-bromophenyl)-propionic acid