pelletierine
pelletierine Basic information
- Product Name:
- pelletierine
- Synonyms:
-
- 1-piperidin-2-ylacetone
- pelletierine
- 2-Acetonylpiperidinepunicineisopelletierine, (.+/-.)-pelletierine
- isopelletierine
- 1-(2-Piperidinyl)-2-propanone
- 1-(2-Piperidyl)-2-propanone
- 2-(2-Oxopropyl)piperidine
- 1-piperidin-2-ylpropan-2-one
- CAS:
- 4396-01-4
- MF:
- C8H15NO
- MW:
- 141.21
- EINECS:
- 224-523-0
- Mol File:
- 4396-01-4.mol
pelletierine Chemical Properties
- Melting point:
- 130-132 °C
- Boiling point:
- 195 °C
- Density
- 0.918±0.06 g/cm3(Predicted)
- storage temp.
- Hygroscopic, -20°C Freezer, Under inert atmosphere
- solubility
- Chloroform (Slightly), Ethyl Acetate (Slightly)
- form
- Oil
- pka
- pK1:9.45 (15°C)
- color
- Colourless to Light Yellow
- Stability:
- Hygroscopic
pelletierine Usage And Synthesis
Description
An alkaloid of this name was discovered by Tanret but when this alkaloid was shown to be (±)-pelletierine, the name was adopted for this particular base isolated from Punica granatum. The alkaloid is an oily liquid which yields a number of well crystalline salts and derivative: the hydrochloride, m.p. 143°C; hydrobromide, m.p. 149°C; picrate, m.p. 147 -8°C and the picrolonate, m.p. 185-6°C. The N-acetyl derivative is an oily liquid, b.p. 110-5°C/0.I mm while the N-benzoyl compound is crystalline with m.p. 72-4°C. The alkaloid may be prepared by the demethylation of methylisopelletierine, the action being revers_x0002_ible.
Definition
ChEBI: Pelletierine is a citraconoyl group.
References
Tanret., Compt. rend., 88, 716 (1879) Tanret., ibid, 90, 696 (1880) Hesse., Rev. trav. Chim., 52, 1005 (1919) Hess, Littman., Annalen, 494, 7 (1932) Wibaut, Kloppenburg, Beets., Rev. trav. Chim., 63, 134 (1944) Anet, Hughes, Ritchie., Nature, 164, 50 I (1949) Galinovsky, Branchetti, Vogl.,Monatsh., 84, 1221 (1953) Galinovsky, Hollinger., ibid, 85, 1012 (1954) Wibaut, Hirschel., Rev. trav. Chim., 75,225 (1956)
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