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Zinchexacyanocobaltate

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Zinchexacyanocobaltate Basic information

Product Name:
Zinchexacyanocobaltate
Synonyms:
  • zinc(II) hexacyanocobaltate(III)
  • Trizinc bis[hexacyanocobaltate(3-)]
  • Zinc cobalticyanide
  • 14049-79-7 Zn3.[Co(CN)6]2 Zinchexacyanocobaltate
  • DOUBLE METAL CYANIDE CATALYST
CAS:
14049-79-7
MF:
Zn3.[Co(CN)6]2
MW:
313.12
Mol File:
14049-79-7.mol
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Zinchexacyanocobaltate Chemical Properties

InChI
InChI=1S/12CN.2Co.3Zn/c12*1-2;;;;;/q;;;;;;;;;;;;2*-3;3*+2
InChIKey
PRTZFTLWWSULFO-UHFFFAOYSA-N
SMILES
[Zn+2].[Zn+2].[Zn+2].[Co-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[Co-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N
EPA Substance Registry System
Cobaltate(3-), hexakis(cyano-.kappa.C)-, zinc (2:3), (OC-6-11)- (14049-79-7)
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Zinchexacyanocobaltate Usage And Synthesis

Definition

Zinc hexacyanocobaltate (ZnHCCo) is a Prussian blue analog. It could be used as a new cathode material for rechargeable LIBs used in grid-scale energy storage and conversion systems via the room temperature co-precipitation process using cost-efficient precursors, which are easily upscaled. Benefiting from the concomitant surface- and diffusion-controlled Li-ion storage, a highly reversible capacity of 121.5 mAh g?1 at 1.25 C and a 96.5% Coulombic efficiency were obtained during the charge/discharge cycling test[1].

References

[1] Kaiqiang Zhang. “A Hybrid Energy Storage Mechanism of Zinc Hexacyanocobaltate-Based Metal–Organic Framework Endowing Stationary and High-Performance Lithium-Ion Storage.” Electronic Materials Letters 15 4 (2019): 444–453.

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