Zinchexacyanocobaltate
Zinchexacyanocobaltate Basic information
- Product Name:
- Zinchexacyanocobaltate
- Synonyms:
-
- zinc(II) hexacyanocobaltate(III)
- Trizinc bis[hexacyanocobaltate(3-)]
- Zinc cobalticyanide
- 14049-79-7 Zn3.[Co(CN)6]2 Zinchexacyanocobaltate
- DOUBLE METAL CYANIDE CATALYST
- CAS:
- 14049-79-7
- MF:
- Zn3.[Co(CN)6]2
- MW:
- 313.12
- Mol File:
- 14049-79-7.mol
Zinchexacyanocobaltate Chemical Properties
- InChI
- InChI=1S/12CN.2Co.3Zn/c12*1-2;;;;;/q;;;;;;;;;;;;2*-3;3*+2
- InChIKey
- PRTZFTLWWSULFO-UHFFFAOYSA-N
- SMILES
- [Zn+2].[Zn+2].[Zn+2].[Co-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[Co-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N
- EPA Substance Registry System
- Cobaltate(3-), hexakis(cyano-.kappa.C)-, zinc (2:3), (OC-6-11)- (14049-79-7)
Zinchexacyanocobaltate Usage And Synthesis
Definition
Zinc hexacyanocobaltate (ZnHCCo) is a Prussian blue analog. It could be used as a new cathode material for rechargeable LIBs used in grid-scale energy storage and conversion systems via the room temperature co-precipitation process using cost-efficient precursors, which are easily upscaled. Benefiting from the concomitant surface- and diffusion-controlled Li-ion storage, a highly reversible capacity of 121.5 mAh g?1 at 1.25 C and a 96.5% Coulombic efficiency were obtained during the charge/discharge cycling test[1].
References
[1] Kaiqiang Zhang. “A Hybrid Energy Storage Mechanism of Zinc Hexacyanocobaltate-Based Metal–Organic Framework Endowing Stationary and High-Performance Lithium-Ion Storage.” Electronic Materials Letters 15 4 (2019): 444–453.
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