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Tetraoctyltin

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Tetraoctyltin Basic information

Product Name:
Tetraoctyltin
Synonyms:
  • tetra-n-octylstannane
  • TETRAOCTYLTIN FOR SYNTHESIS
  • tetraoctyl-stannan
  • tetraoctyl-ti
  • TIN TETRAOCTYL
  • TETRA-N-OCTYLTIN
  • TETRA-N-OCTYLTIN(IV)
  • TETRAOCTYLSTANNANE
CAS:
3590-84-9
MF:
C32H68Sn
MW:
571.59
EINECS:
222-733-7
Mol File:
3590-84-9.mol
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Tetraoctyltin Chemical Properties

Boiling point:
224°C 1mm
Density 
0,98 g/cm3
vapor pressure 
0Pa at 25℃
refractive index 
1.4677
Flash point:
102°C
storage temp. 
Store below +30°C.
solubility 
Chloroform (Soluble), Ethyl Acetate (Sparingly)
form 
Oil
color 
Off-White to Yellow
Specific Gravity
0.961
Hydrolytic Sensitivity
1: no significant reaction with aqueous systems
InChI
1S/4C8H17.Sn/c4*1-3-5-7-8-6-4-2;/h4*1,3-8H2,2H3;
InChIKey
JTGNPNLBCGBCMP-UHFFFAOYSA-N
SMILES
[Sn](CCCCCCCC)(CCCCCCCC)(CCCCCCCC)CCCCCCCC
LogP
9.09 at 22.3℃
CAS DataBase Reference
3590-84-9(CAS DataBase Reference)
EPA Substance Registry System
Stannane, tetraoctyl- (3590-84-9)
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Safety Information

Risk Statements 
36/37
Safety Statements 
24
WGK Germany 
WGK 2
TSCA 
TSCA listed
Storage Class
6.1C - Combustible, acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications
Aquatic Chronic 4
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Toxicity
mouse,LDLo,parenteral,34gm/kg (34000mg/kg),PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE),Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 239, Pg. 1091, 1954.
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Tetraoctyltin Usage And Synthesis

Uses

Tetraoctyltin was coupled to C-H bonds of 2-aryl- and 2-benzyl-substituted 4,4-dimethyl-2-oxazolines and pyridines to give the benzene ring-alkylated products in good yields by using 5 mol % Pd(OAc)2 as the catalyst.

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