Basic information Reactions Safety Supplier Related

[mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%

Basic information Reactions Safety Supplier Related

[mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99% Basic information

Product Name:
[mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%
Synonyms:
  • [μ-Bis(diphenylphosphino)methane]dichlorodigold(I),98%
  • (DPPM)(AuCl)2
  • Bis(chlorogold) bis(diphenylphosphino)methane
  • [μ-Bis(diphenylphosphino) methane]dichlorodigold(I), 99%
  • [Mu-Bis(diphenylphosphino)Methane]dichlorodigold(III)
  • [mu-Bis(diphenylphosphino)methane]dichlorodigold(I), 99%
  • [mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%
  • [Mu-Bis(diphenylphosphino)Methane]dichlorodigold(I),99%
CAS:
37095-27-5
MF:
C25H22P2.2AuCl
MW:
849.243
Product Categories:
  • Au
  • organometallic complex
Mol File:
37095-27-5.mol
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[mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99% Chemical Properties

Melting point:
271-272℃
form 
Powder
color 
white
InChI
InChI=1S/C25H22P2.2Au.2ClH/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25;;;;/h1-20H,21H2;;;2*1H/q;2*+1;;/p-2
InChIKey
JNPUWTQJFLJEJC-UHFFFAOYSA-L
SMILES
[Au]Cl.[Au]Cl.P(CP(C1C=CC=CC=1)C1C=CC=CC=1)(C1C=CC=CC=1)C1=CC=CC=C1
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Safety Information

WGK Germany 
3
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[mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99% Usage And Synthesis

Reactions

  1. Catalyst used with chiral counter-ion for asymmetric hydroalkoxylation.
  2. Catalyst used for intramolecular acetylene Schmidt reaction.

Uses

Used for

  • Pharmacological studies involving the anticancer activity of gold(I)-phosphine complexes as autophagy-inducing agents
  • Triplet luminescent light emitting diodes with low turn-on voltage

Catalyst for:
  • Stereoselective preparation of vinyltetrahydrofuran via intramolecular hydroalkoxylation
  • Hydroamination and hydroalkoxylation reactions
  • Asymmetric transition metal catalysis
  • Gold(I) catalyzed intramolecular Schmidt reactions of homopropargyl azides

reaction suitability

core: gold
reagent type: catalyst

[mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%Supplier

Shandong Carbene New Material Technology Co., Ltd Gold
Tel
19153017839; 19153017839
Email
1041357006@qq.com
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Email
jkinfo@jkchemical.com
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Email
cynthiachem@163.com
Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
150-2103-5486 18017383231
Email
983544897@qq.com
Amatek Scientific Co. Ltd.
Tel
0512-56316828 4008675858
Email
sales@amateksci.com
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