4-Bromo-4'-hydroxybiphenyl Chemical Properties

Melting point:

164-166 °C(lit.)

Boiling point:

355.5±17.0 °C(Predicted)

Density 

1.4188 (rough estimate)

refractive index 

1.5130 (estimate)

storage temp. 

Sealed in dry,Room Temperature

form 

powder to crystal

pka

9.70±0.15(Predicted)

color 

White to Almost white

Water Solubility 

Soluble in water (partly), and methanol.

InChI

InChI=1S/C12H9BrO/c13-11-5-1-9(2-6-11)10-3-7-12(14)8-4-10/h1-8,14H

InChIKey

ARUBXNBYMCVENE-UHFFFAOYSA-N

SMILES

C1(C2=CC=C(Br)C=C2)=CC=C(O)C=C1

CAS DataBase Reference

29558-77-8(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39

WGK Germany 

3

HS Code 

29081990

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

4-Bromo-4'-hydroxybiphenyl Usage And Synthesis

Chemical Properties

White or cream powder

Uses

A biphenyl starting material. 4?-Bromo-(1,1?-biphenyl)-4-ol is a useful intermediate. Vinylation of 4-bromo-4?-hydroxybiphenyl and ethyl acrylate using Pd (OAc) 2/PPh 3 catalyst was studied. Ethyl 4-(4?-hydroxyphenyl) cinnamate was formed as the vinylation product, while, 4-hydroxybiphenyl and ethyl cinnamate were formed as side products. Preparation of 4-cyano-4'-hydroxybiphenyl This was prepared from 4-bromo-4'-benzenesulphonyloxybiphenyl by first hydrolysing it to 4-bromo-4-hydroxybiphenyl using sodium hydroxide dissolved in a mixture of water and dioxan. The syntheses of the Nanocomposite dendrimers based on cyclic phosphazene cores: Amorphous materials, were accomplished by following a modified literature procedure by reacting phosphonitrilic chloride trimer with 4-bromophenol or 4-bromo-4?-hydroxybiphenyl, respectively, in the presence of K 2 CO 3 in tetrahydrofuran (THF).

4-Bromo-4'-hydroxybiphenyl(29558-77-8)Related Product Information

• Bifendate
• trans-Bifenthtin
• 2-Bromobiphenyl
• Decabromodiphenyl oxide
• Phenol
• 2,3,3',4,4',5-HEXACHLOROBIPHENYL
• 4-Bromobiphenyl
• Phenol Red
• 4-Phenylphenol
• 3-Bromoanisole
• 4-Aminophenol
• FIREMASTER BP-6
• Nonylphenol
• Bromine
• 4-Bromo-4'-methoxybiphenyl
• 4-ACETOXY-4'-BROMOBIPHENYL
• 4'-BROMO-4-(TRIFLUOROMETHOXY)BIPHENYL
• 4-Benzyloxy-4'-bromo-biphenyl