Basic information Safety Supplier Related

Chloroplatinic acid hydrate

Basic information Safety Supplier Related

Chloroplatinic acid hydrate Basic information

Product Name:
Chloroplatinic acid hydrate
Synonyms:
  • hydrogenhexachloroplatinate(iv)hydrate,reagentacs
  • Hydrogenhexachloroplatinum(IV)hydrate
  • PLATINUM(IV) CHLORIDE ACID HEXAHYDRATE
  • PLATINUM(IV) CHLORIDE HEXAHYDRATE
  • PLATINUM CHLORIDE, HEXAHYDRATE
  • PLATINUM CHLORIDE
  • PLATINIC CHLORIDE HEXAHYDRATE
  • Hydrogen hexachloroplatinate(IV) hydrate, ca. 40% Pt
CAS:
26023-84-7
MF:
Cl6H3OPt-
MW:
426.81
EINECS:
607-848-6
Mol File:
26023-84-7.mol
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Chloroplatinic acid hydrate Chemical Properties

Melting point:
60 °C(lit.)
Density 
2.43 g/mL at 25 °C(lit.)
storage temp. 
2-8°C
solubility 
H2O: 0.5 M at 20 °C, clear, orange
form 
powder and chunks
color 
orange
Specific Gravity
2.43
Water Solubility 
Soluble in water, ethanol, ether, ethyl acetate and acetone. Insoluble in nitric acid.
Sensitive 
Hygroscopic
Merck 
14,7526
Exposure limits
ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
CAS DataBase Reference
26023-84-7(CAS DataBase Reference)
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Safety Information

Hazard Codes 
T
Risk Statements 
25-34-42/43
Safety Statements 
22-26-36/37/39-45
RIDADR 
UN 2507 8/PG 3
WGK Germany 
1
RTECS 
TP1510000
3-8-10
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
28439000

MSDS

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Chloroplatinic acid hydrate Usage And Synthesis

Chemical Properties

orange to brown lumps

Uses

Catalysis, electroplating, photography, platinum mirrors, printing for etching of zinc, producing fine color in glass and porcelain, indelible ink, microscopy.Dihydrogen hexachloroplatinate(IV) hexahydrate is used for the determination of potassium. It is also used for the purification of platinum by treating it with ammonium chloride followed by heating of ammonium hexachloroplatinate with hydrogen yields elemental platinum. It also finds application in catalysis, electroplating, photography, platinum mirrors, printing for etching of zinc, producing fine color in glass and porcelain, indelible ink and microscopy. It is a precursor for the preparation of other platinum catalysts. In addition to this, it is also used as an analytical reagent.

General Description

Chloroplatinic acid hydrate is the most readily available compound of platinum. It may be prepared by dissolving platinum in aqua regia. Thermogravimetric analysis of this compound has been reported. The analysis shows the loss of water followed by formation of platinum tetrachloride (PtCl4) at 220 °C and β-PtCl2 at 350 °C finally decomposing to platinum metal at 500 °C.

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