Allylboronic acid pinacol ester
Allylboronic acid pinacol ester Basic information
- Product Name:
- Allylboronic acid pinacol ester
- Synonyms:
-
- 2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Allylboronic acid pinacol ester 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Allylboronic acid pinacol ester 97%
- 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)
- 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane
- 4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane
- Allyl pinacol boronate
- Pinacolyl 2-propenylboronate
- CAS:
- 72824-04-5
- MF:
- C9H17BO2
- MW:
- 168.04
- EINECS:
- 672-877-3
- Product Categories:
-
- Alkyl Boronate Esters
- Boronate Esters
- Olefin
- Boronic Acids and Derivatives
- Chemical Synthesis
- Organometallic Reagents
- Organoborons
- B (Classes of Boron Compounds)
- Boronic Acids Esters
- CHIRAL CHEMICALS
- Mol File:
- 72824-04-5.mol
Allylboronic acid pinacol ester Chemical Properties
- Boiling point:
- 50-53 °C/5 mmHg (lit.)
- Density
- 0.896 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.4268(lit.)
- Flash point:
- 115 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform, Methanol (Slightly)
- form
- Liquid
- color
- Clear colorless
- Water Solubility
- Not miscible or difficult to mix in water.
- BRN
- 4244068
- CAS DataBase Reference
- 72824-04-5(CAS DataBase Reference)
Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 10-36/37/38
- Safety Statements
- 26-36
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29310095
MSDS
- Language:English Provider:2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
Allylboronic acid pinacol ester Usage And Synthesis
Chemical Properties
Clear corless liquid
Uses
Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.
Uses
Allylboronic acid pinacol ester can act as reagent used for Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis; Intermolecular radical additions; Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids and Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes ; Nucleic acid-templated energy transfer leading to a photorelease reaction .
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Allylboronic acid pinacol ester(72824-04-5)Related Product Information
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- Diethyl phthalate
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- Tris(trimethylsilyl)phosphate
- Allyl chloride
- Pinacol
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- DIHYDRODICYCLOPENTADIENYL ACRYLATE
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