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N,N'-Diphenylformamidine

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N,N'-Diphenylformamidine Basic information

Product Name:
N,N'-Diphenylformamidine
Synonyms:
  • LABOTEST-BB LTBB000577
  • DIPHENYLFORMAMIDINE
  • N-(Phenyliminomethyl)aniline
  • N-Phenyl(anilinomethane)imine
  • N,N'-Diphenylformamidine,98%
  • N1,N2-diphenylformamidine
  • N,N'-diphenylformimidamide
  • N,N'-Diphenylformamidine
CAS:
622-15-1
MF:
C13H12N2
MW:
196.25
EINECS:
210-720-9
Product Categories:
  • Aromatic Phenylacetic Acids and Derivatives
  • Imines/Amidines
  • Nitrogen Compounds
  • Organic Building Blocks
Mol File:
622-15-1.mol
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N,N'-Diphenylformamidine Chemical Properties

Melting point:
136-139 °C(lit.)
Boiling point:
323.14°C (rough estimate)
Density 
1.1265 (rough estimate)
refractive index 
1.5014 (estimate)
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Crystalline Powder or Crystals
pka
7.70±0.10(Predicted)
color 
White to yellow to beige
Sensitive 
Moisture Sensitive
BRN 
511953
CAS DataBase Reference
622-15-1(CAS DataBase Reference)
NIST Chemistry Reference
N,n'-diphenylformamidine(622-15-1)
EPA Substance Registry System
N,N'-Diphenylformamidine (622-15-1)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
22-24/25
WGK Germany 
3
RTECS 
PB7705000
10-21
TSCA 
Yes
HS Code 
29215900

MSDS

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N,N'-Diphenylformamidine Usage And Synthesis

Chemical Properties

white to yellowish crystals or cryst. powder

Uses

N,N''-Diphenylformamidine is used in the preparation of polyfluoro benzoxazole polymethine dyes which are used as fluorescent labels for biomolecules.

Uses

N,N′-Diphenylformamidine was used in the microwave-assisted synthesis of 5-aminopyrazol-4-yl ketones. It was also used in the preparation of monomethine dyes containing imide functional groups.

Synthesis Reference(s)

Journal of the American Chemical Society, 76, p. 3978, 1954 DOI: 10.1021/ja01644a034

General Description

N,N′-Diphenylformamidine is an N,N-disubstituted formamide and it forms adducts with phosgeneand oxalyl chloride.

Purification Methods

The hydrate is obtained from aqueous EtOH. [Beilstein 12 H 236, 12 IV 372.]

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