BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Chemical Properties

Melting point:

160-165 °C (dec.) (lit.)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

solubility 

Soluble in organic solvents.

form 

crystal

color 

yellow

Sensitive 

moisture sensitive, store cold

InChI

InChI=1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;

InChIKey

WBRREXQCZAFSKS-XFCUKONHSA-L

SMILES

C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.Cl[Ir].Cl[Ir] |^1:3,4,11,12,19,20,27,28|

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39

WGK Germany 

3

TSCA 

No

HS Code 

28439000

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich

BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Usage And Synthesis

Chemical Properties

Yellow solid

Uses

Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions.

reaction suitability

core: iridium
reagent type: catalyst

BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER(12246-51-4)Related Product Information

• cis-Cyclooctene
• Iridium
• BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER