BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER CAS#: 12246-51-4

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BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Basic information Safety Supplier Related

BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Basic information

Product Name:

BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Synonyms:

Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9%
Chlorobis(cyclooctene)iridium dimer
Chlorobis(cyclooctene)iridium(Ⅰ) dimer
Chlorobis(cyclooctene)iridiuM(Ⅰ) diMer, 43% Ir, Product of UMicore
Chlorobis(cyclooctene)iridium(I)dimer 97%
Di-μ-chloro(tetramethyl)diiridium - (1Z)-cyclooctene (1:4)
Chlorobis(cyclooctene)iridium(I)
CHLOROBIS(CYCLOOCTENE)IRIDIUM (I) DIMER

CAS:

12246-51-4

MF:

C32H56Cl2Ir28*

MW:

896.13

Product Categories:

Ir
organometallic complex

Mol File:

12246-51-4.mol

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BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Chemical Properties

Melting point:: 160-165 °C (dec.) (lit.)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Soluble in organic solvents.
form: crystal
color: yellow
Sensitive: moisture sensitive, store cold

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Safety Information

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
TSCA: No
HS Code: 28439000

MSDS

Language:English Provider:ACROS
Language:English Provider:SigmaAldrich

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BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Usage And Synthesis

Chemical Properties

Yellow solid

Uses

Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions.

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