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ChemicalBook >  Product Catalog >  Organic Chemistry >  (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Basic information

Product Name:
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
Synonyms:
  • (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
  • (S,S)-ME-BPE
  • (-)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane, Kanata purity
  • (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane,98+%(S,S)-Me-BPE
  • 1,2-Bis[(2S,5S)-2,5-diMethyl-1-phospholanyl]ethane, 97+%
  • (-)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane, 97% (S,S-Me-BPE)
  • (-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane (S,S)-Me-BPE
  • 1,2-Bis[(2S,5S)-2,5-dimethyl-1-phospholanyl]ethane
CAS:
136779-26-5
MF:
C14H28P2
MW:
258.32
Product Categories:
  • organophosphine ligand
Mol File:
136779-26-5.mol
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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Chemical Properties

Boiling point:
64-67 °C0.06 mm Hg
alpha 
-263° ±3° (c 1, hexane)
Density 
0.938 g/mL at 25 °C
refractive index 
n20/D 1.535
form 
liquid
color 
colorless to pale-yellow
Sensitive 
Air Sensitive
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Safety Information

Hazard Codes 
F
Risk Statements 
11-17
Safety Statements 
24/25
RIDADR 
UN 2845 4.2/PG 1
WGK Germany 
3
HazardClass 
4.2
HS Code 
29310099

MSDS

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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Usage And Synthesis

Reaction

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.

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