2,4-Dibromoaniline Chemical Properties

Melting point:

78-80 °C (lit.)

Boiling point:

156 °C (24 mmHg)

Density 

2.26

refractive index 

1.5800 (estimate)

Flash point:

156°C/24mm

storage temp. 

Store below +30°C.

Water Solubility 

Insoluble in water

form 

powder to crystal

pka

1.83±0.10(Predicted)

color 

White to Light yellow

BRN 

2206653

CAS DataBase Reference

615-57-6(CAS DataBase Reference)

NIST Chemistry Reference

Benzenamine, 2,4-dibromo-(615-57-6)

EPA Substance Registry System

2,4-Dibromoaniline (615-57-6)

Safety Information

Hazard Codes 

Xn,Xi,N,T

Risk Statements 

36/37/38-33-20/21/22-51/53-25

Safety Statements 

36/37/39-26-61-45

RIDADR 

2811

WGK Germany 

3

TSCA 

T

HazardClass 

6.1

PackingGroup 

III

HS Code 

29214210

MSDS

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2,4-Dibromoaniline Usage And Synthesis

Chemical Properties

beige powder

Uses

2,4-Dibromoaniline is used in preparation of glycopeptides and targeted bifunctional degraders.

Uses

2,4-Dibromoaniline can be used as:

• A starting material to synthesize acetylenic amine by reacting with trimethylsilylacetylene, which is used as a ligand to prepare the bis-amido complex of Ti(IV).
• A substrate in the Pd-catalyzed ortho-selective cross-coupling reactions of dihaloarenes with Grignard reagents.
• A reactant to prepare dialkyl-substituted aminoaryl sulfides using a Grignard reagent.
• A starting material to synthesize substituted 2-mercapto benzimidazoles.

Purification Methods

Crystallise the aniline from aqueous EtOH. The picrate has m 124o. [Beilstein 12 H 655, 12 I 326, 12 II 356, 12 III 1471, 12 IV 1532.]

2,4-Dibromoaniline(615-57-6)Related Product Information

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