(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Chemical Properties

alpha 

-100° ±5° (c 0.5, CHCl3)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

Powder

color 

orange

Safety Information

Risk Statements 

36/37/38

Safety Statements 

26-36/37/39

WGK Germany 

3

F 

10

HS Code 

29319090

MSDS

• Language:English Provider:SigmaAldrich

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Usage And Synthesis

Chemical Properties

Red crystal

Uses

(R)-1-[(S_P)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:

• To prepare iridium metal complex (Ir^IJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
• In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.

Reactions

1. Ligand for asymmetric hydroformylation reactions
2. Ligand for asymmetric intramolecular amide arylation
3. Ligand for enantioselective 1,6-conjugate addition of Grignard reagents to linear dienolates
4. Ligand for enantioselective synthesis of vicinal dialkyl arrays
5. Ligand for asymmetric conjugate addition of Grignard reagents to chromones .

General Description

sold in collaboration with Solvias AG

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE(158923-09-2)Related Product Information

• ETHYLDIPHENYLPHOSPHINE
• (S)-1-[(1R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
• (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
• 1,3-BIS(DIMETHYLPHOSPHINO)PROPANE
• DICYCLOHEXYLPHOSPHINE
• 1,3-BIS(PHOSPHINO)PROPANE
• TRIISOPROPYLPHOSPHINE
• TRIHEXYLPHOSPHINE