(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Basic information
- Product Name:
- (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
- Synonyms:
-
- (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
- (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane
- (4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-prop-2-enyl-1,3,2-oxazasilolidine
- (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine
- 1-Oxa-3-aza-2-silacyclopentane,2-chloro-3,4-dimethyl-5-pheny...
- 1-Oxa-3-aza-2-silacyclopentane, 2-chloro-3,4-dimethyl-5-phenyl-2-(2-propen-1-yl)-, (4S,5S)-
- CAS:
- 447440-43-9
- MF:
- C13H18ClNOSi
- MW:
- 267.83
- Product Categories:
-
- organosilicon compound
- Mol File:
- 447440-43-9.mol
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(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Chemical Properties
- Density
- 1.095 g/mL at 25 °C
- refractive index
- n20/D1.517
- Flash point:
- 38℃
- pka
- 4.43±0.60(Predicted)
- Specific Gravity
- 1.01
- optical activity
- [α]20/D 72.5°, c = 0.6 in ethanol (200 proof)
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- Sensitive
- moisture sensitive, store cold
- Boiling point:
- 120°C/5 mmHg
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Safety Information
- Hazard Codes
- F,Xi
- Risk Statements
- 10-15-36/37/38
- Safety Statements
- 26
- RIDADR
- UN 3132 / PGII
- WGK Germany
- 3
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(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Usage And Synthesis
Reaction
Versatile reagent for the enantioselective allylation of aldehydes and hydrazones.
Uses
Leighton′s Strained Silacycles: Powerful Enantioselective Allylation Reagents
- Practical, enantioselective allylation of acylhydrazones
- Enantioselective allylation of ketimines: synthesis of tertiary carbinamines
General Description
This product is a mixture of diastereomers.
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINESupplier
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