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1,2-PHENYLENE PHOSPHOROCHLORIDITE

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1,2-PHENYLENE PHOSPHOROCHLORIDITE Basic information

Product Name:
1,2-PHENYLENE PHOSPHOROCHLORIDITE
Synonyms:
  • 1,3,2-Benzodioxaphosphole,2-chloro-
  • 2-benzodioxaphosphole,2-chloro-3
  • O-PHENYLENE PHOSPHOROCHLORIDITE
  • 1,2-PHENYLENE PHOSPHOROCHLORIDITE
  • 2-CHLORO-1,3,2-BENZODIOXAPHOSPHOLE
  • Catechyl phosphorus chloride~2-Chloro-1,3,2-benzodioxaphosphole
  • 1,2-Phenylene phosphorochloridite, 98+%
  • CATECHYL PHOSPHORUS CHLORIDE
CAS:
1641-40-3
MF:
C6H4ClO2P
MW:
174.52
EINECS:
216-690-3
Product Categories:
  • Phospholipids - 13C & 2H
  • Phosphorylating and Phosphitylating Agents
  • Aromatics
  • Heterocycles
Mol File:
1641-40-3.mol
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1,2-PHENYLENE PHOSPHOROCHLORIDITE Chemical Properties

Melting point:
30-35 °C(lit.)
Boiling point:
80 °C20 mm Hg(lit.)
Density 
1.466 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.571(lit.)
Flash point:
>230 °F
storage temp. 
0-6°C
solubility 
Benzene (Slightly), Chloroform (Slightly)
form 
solid
Sensitive 
Moisture Sensitive
BRN 
135455
Stability:
Moisture Sensitive
CAS DataBase Reference
1641-40-3(CAS DataBase Reference)
EPA Substance Registry System
1,3,2-Benzodioxaphosphole, 2-chloro- (1641-40-3)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
10-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
II

MSDS

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1,2-PHENYLENE PHOSPHOROCHLORIDITE Usage And Synthesis

Chemical Properties

Colourless Liquid Which Solidifies at Low Temperature

Uses

Highly reactive cyclic phosphitylating reagent which provides fast coupling rates, and hydrolytic cleavage occurs more readily than with acyclic analogs

Uses

  • Catalyst in synthesis of bakkane sesquiterpenes
  • Reactant in reversible halogen-halogen ligand substitution at room temperature, and in irreversible halogen-O substitution at higher temperatures
  • Reactant in preparation of gold(I) trimethoxybenzonitrile phosphine isolated precatalysts
  • Reactant for preparation of pyrroles by TMSOTf-catalyzed Arbuzov reaction
  • Phosphorylation agent
  • Reactant for reparation of vinyl-substituted spirophosphoranes and vinylphosphonates via Markovnikov addition

1,2-PHENYLENE PHOSPHOROCHLORIDITESupplier

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