1,2-PHENYLENE PHOSPHOROCHLORIDITE
1,2-PHENYLENE PHOSPHOROCHLORIDITE Basic information
- Product Name:
- 1,2-PHENYLENE PHOSPHOROCHLORIDITE
- Synonyms:
-
- 1,3,2-Benzodioxaphosphole,2-chloro-
- 2-benzodioxaphosphole,2-chloro-3
- O-PHENYLENE PHOSPHOROCHLORIDITE
- 1,2-PHENYLENE PHOSPHOROCHLORIDITE
- 2-CHLORO-1,3,2-BENZODIOXAPHOSPHOLE
- Catechyl phosphorus chloride~2-Chloro-1,3,2-benzodioxaphosphole
- 1,2-Phenylene phosphorochloridite, 98+%
- CATECHYL PHOSPHORUS CHLORIDE
- CAS:
- 1641-40-3
- MF:
- C6H4ClO2P
- MW:
- 174.52
- EINECS:
- 216-690-3
- Product Categories:
-
- Phospholipids - 13C & 2H
- Phosphorylating and Phosphitylating Agents
- Aromatics
- Heterocycles
- Mol File:
- 1641-40-3.mol
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1,2-PHENYLENE PHOSPHOROCHLORIDITE Chemical Properties
- Melting point:
- 30-35 °C(lit.)
- Boiling point:
- 80 °C20 mm Hg(lit.)
- Density
- 1.466 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.571(lit.)
- Flash point:
- >230 °F
- storage temp.
- 0-6°C
- solubility
- Benzene (Slightly), Chloroform (Slightly)
- form
- solid
- Sensitive
- Moisture Sensitive
- BRN
- 135455
- Stability:
- Moisture Sensitive
- CAS DataBase Reference
- 1641-40-3(CAS DataBase Reference)
- EPA Substance Registry System
- 1,3,2-Benzodioxaphosphole, 2-chloro- (1641-40-3)
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Safety Information
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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1,2-PHENYLENE PHOSPHOROCHLORIDITE Usage And Synthesis
Chemical Properties
Colourless Liquid Which Solidifies at Low Temperature
Uses
Highly reactive cyclic phosphitylating reagent which provides fast coupling rates, and hydrolytic cleavage occurs more readily than with acyclic analogs
Uses
- Catalyst in synthesis of bakkane sesquiterpenes
- Reactant in reversible halogen-halogen ligand substitution at room temperature, and in irreversible halogen-O substitution at higher temperatures
- Reactant in preparation of gold(I) trimethoxybenzonitrile phosphine isolated precatalysts
- Reactant for preparation of pyrroles by TMSOTf-catalyzed Arbuzov reaction
- Phosphorylation agent
- Reactant for reparation of vinyl-substituted spirophosphoranes and vinylphosphonates via Markovnikov addition
1,2-PHENYLENE PHOSPHOROCHLORIDITESupplier
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