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CIS-3-HEXENYL PROPIONATE

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CIS-3-HEXENYL PROPIONATE Basic information

Product Name:
CIS-3-HEXENYL PROPIONATE
Synonyms:
  • (3Z)-3-Hexenyl propionate
  • (Z)-3-Hexen-1-ol, propanoate
  • (Z)-3-hexenyl propanoate
  • (z)-3-hexenylpropionate
  • green note propionate
  • 3-Hexen-1-ol, propanoate, (Z)-
  • 3-Hexen-1-ol, propionate, (Z)-
  • beta,gamma-Hexenyl propanoate, cis
CAS:
33467-74-2
MF:
C9H16O2
MW:
156.22
EINECS:
251-533-2
Product Categories:
  • Alphabetical Listings
  • Flavors and Fragrances
  • G-H
Mol File:
33467-74-2.mol
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CIS-3-HEXENYL PROPIONATE Chemical Properties

Melting point:
-57.45°C (estimate)
Boiling point:
83 °C/17 mmHg(lit.)
Density 
0.887 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.43(lit.)
FEMA 
3933 | CIS-3-HEXENYL PROPIONATE
Flash point:
66 °C
storage temp. 
Inert atmosphere,Room Temperature
Odor
at 100.00 %. green fresh fruity apple pear vegetable melon banana peach
Appearance
Colorless to light yellow Liquid
Odor Type
green
biological source
synthetic
JECFA Number
1274
Major Application
flavors and fragrances
Cosmetics Ingredients Functions
PERFUMING
InChI
1S/C9H16O2/c1-3-5-6-7-8-11-9(10)4-2/h5-6H,3-4,7-8H2,1-2H3/b6-5-
InChIKey
LGTLDEUQCOJGFP-WAYWQWQTSA-N
SMILES
[H]\C(CC)=C(/[H])CCOC(=O)CC
LogP
2.95
CAS DataBase Reference
33467-74-2(CAS DataBase Reference)
NIST Chemistry Reference
3-Hexen-1-ol, propanoate, (z)-(33467-74-2)
EPA Substance Registry System
3-Hexen-1-ol, propanoate, (3Z)- (33467-74-2)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
MP8645100
TSCA 
TSCA listed
Storage Class
10 - Combustible liquids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Toxicity
rabbit,LD50,skin,> 5gm/kg (5000mg/kg),Food and Cosmetics Toxicology. Vol. 17, Pg. 805, 1979.
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CIS-3-HEXENYL PROPIONATE Usage And Synthesis

Chemical Properties

(Z)-3-Hexenyl propionate has a green, waxy odor with a vegetable character.

Occurrence

Reported found in thyme, black tea, plum and fresh mango

Uses

flavors and fragrances

Definition

ChEBI: Cis-3-Hexenyl propanoate is a carboxylic ester.

Taste threshold values

Taste characteristics at 5 ppm: green, apple and pear with an oily, waxy, slightly citrus note

Synthesis

Cis-3-hexenyl propionate is prepared from cis-3-Hexenol and Propionicacid by azeotropic esterification.

CIS-3-HEXENYL PROPIONATESupplier

jiliang chemicals
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