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N,N-Dimethylethylenediamine

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N,N-Dimethylethylenediamine Basic information

Product Name:
N,N-Dimethylethylenediamine
Synonyms:
  • N-(2-Aminoethyl)-N,N-dimethylamine
  • N,N-Dimethyl-1,2-diaminoethane
  • N,N'-Dimethyl-1,2-ethandiamine
  • N,N-Dimethyl-1,2-ethylenediamine
  • ACRYLIC ACID 2-(DIMETHYLAMINO)ETHYL ESTER
  • ACRYLIC ACID 2-(N,N-DIMETHYLAMINO)ETHYL ESTER
  • 2-(DIMETHYLAMINO)ETHYL ACRYULATE
  • 2-DIMETHYLAMINOETHYLAMINE
CAS:
108-00-9
MF:
C4H12N2
MW:
88.15
EINECS:
203-541-2
Product Categories:
  • Building Blocks
  • Chemical Synthesis
  • Nitrogen Compounds
  • Organic Building Blocks
  • Polyamines
  • 108-00-9
  • john's
Mol File:
108-00-9.mol
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N,N-Dimethylethylenediamine Chemical Properties

Melting point:
-70 °C
Boiling point:
104-106 °C (lit.)
Density 
0.807 g/mL at 20 °C (lit.)
vapor pressure 
0.35 psi ( 20 °C)
refractive index 
n20/D 1.438(lit.)
Flash point:
75 °F
storage temp. 
Store below +30°C.
form 
Liquid
pka
9.59±0.10(Predicted)
color 
Clear colorless to pale yellow
PH
11.4 (10g/l, H2O, 20℃)
explosive limit
1.3-10.8%(V)
Water Solubility 
MISCIBLE
Sensitive 
Hygroscopic
BRN 
605279
CAS DataBase Reference
108-00-9(CAS DataBase Reference)
NIST Chemistry Reference
1,2-Ethanediamine, N,N-dimethyl-(108-00-9)
EPA Substance Registry System
1,2-Ethanediamine, N,N-dimethyl- (108-00-9)
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Safety Information

Hazard Codes 
T+,F,C
Risk Statements 
24/25-26-34-35-21/22-11-36/37-10
Safety Statements 
26-28-36/37/39-45-36-28A-23-16
RIDADR 
UN 3302 6.1/PG 2
WGK Germany 
2
RTECS 
KH8608250
8
Autoignition Temperature
225 °C
Hazard Note 
Highly Flammable/Corrosive/Harmful
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29212900
Toxicity
LD50 orally in Rabbit: 1135 mg/kg

MSDS

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N,N-Dimethylethylenediamine Usage And Synthesis

Description

N,N'-Dimethylethylenediamine is used in DNA binding effect. It is used to enhance the adsorption of carbon dioxide. It acts as a ligand and form coordination complex such as dinitrato(N,N'-dimethyl-1,2-ethanediamine)copper(II) and dichloro(1,4-bis-(diphenyl phosphino)butane)-(1,2-ethylenediamine)ruthenium(II).

Chemical Properties

clear colorless to pale yellow liquid

Uses

It finds its application as an intermediate in the synthesis of Cefotiam. It is also used as a catalyst in the synthesis of allylic nitro compounds.

Uses

N,N-Dimethylethylenediamine is a bidentate ligand that can be used:

  • To synthesize Schiff base ligands to prepare their zinc alkyl and zinc alkoxide complexes that initiate ring-opening polymerization of lactides.
  • As a ligand to prepare copper azido polymers.
  • In the synthesis of naphthalimides such as amonafide, an antitumor agent.
  • As the receptor in building fluorescent signaling systems to perturb the photoinduced intramolecular electron transfer (PET) process from the nitrogen lone-pair to the fluorophore.

Solubility in organics

N,N'-Dimethylethylenediamine is miscible with chloroform and dichloromethane. Incompatible with acids, chlorides, anhydrides, strong oxidising agents and carbon dioxide.

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