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2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE

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2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Basic information

Product Name:
2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE
Synonyms:
  • 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE
  • 2-(CHLOROMETHYL)ALLYL-TRIMETHYLSILANE
  • 2-(TRIMETHYLSILYLMETHYL)ALLYL CHLORIDE
  • [2-(Chloromethyl)-2-propenyl]trimethylsilane
  • 2-(Trimethylsilylmethyl)-2-propenyl chloride
  • 2-(Trimethylsilylmethyl)-3-chloro-1-propene
  • 2-Methylene-3-chloropropyltrimethylsilane
  • 2-(Chloromethyl)-3-trimethylsilyl-1-propene, 2-(Trimethylsilylmethyl)allyl chloride
CAS:
18388-03-9
MF:
C7H15ClSi
MW:
162.73
Mol File:
18388-03-9.mol
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2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Chemical Properties

Boiling point:
162-163 °C/768 mmHg (lit.)
Density 
0.899 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.453(lit.)
Flash point:
110 °F
storage temp. 
2-8°C
solubility 
Chloroform, Methanol (Slightly)
form 
Oil
color 
Clear Colourless
Specific Gravity
0.899
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
1747038
Stability:
Moisture Sensitive
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Safety Information

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
26-36
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
TSCA 
No
HazardClass 
3.2
PackingGroup 
III

MSDS

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2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Usage And Synthesis

Uses

2-??(Chloromethyl)??allyl-??trimethylsilane is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-??(Chloromethyl)??allyl-??trimethylsilane was used in catalytic Sakurai reaction of a,??b-??enones.

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