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LITHIUM TETRACHLOROCUPRATE

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LITHIUM TETRACHLOROCUPRATE Basic information

Product Name:
LITHIUM TETRACHLOROCUPRATE
Synonyms:
  • LITHIUM TETRACHLOROCUPRATE
  • LITHIUM TETRACHLOROCUPRATE(II)
  • DILITHIUM TETRACHLOROCUPRATE
  • DI-LITHIUM TETRACHLOROCUPRATE(II)
  • Dilithium tetrachlorocuprate(II) solution
  • DILITHIUM TETRACHLOROCUPRATE, 0.1M SOLUT ION IN TETRAHYDROFURAN
  • 0.1MinTHF
  • Dilithium tetrachlorocuprate, 0.1 M solution in THF
CAS:
15489-27-7
MF:
Cl4CuLi-
MW:
212.29
EINECS:
203-726-8
Product Categories:
  • halometallate salt
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • CopperMetal and Ceramic Science
  • Lithium Salts
  • Salts
Mol File:
15489-27-7.mol
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LITHIUM TETRACHLOROCUPRATE Chemical Properties

Boiling point:
66°C
Density 
0.91 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
Flammables area
solubility 
Difficult to mix.
form 
Liquid
Specific Gravity
0.91
color 
Dark orange
Sensitive 
Moisture Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
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Safety Information

Hazard Codes 
F,Xi,Xn
Risk Statements 
11-19-36/37-40
Safety Statements 
16-29-33-46-37-36-13
RIDADR 
UN 1993 3/PG 2
WGK Germany 
1
10-21
HazardClass 
3
PackingGroup 
II
HS Code 
28429090

MSDS

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LITHIUM TETRACHLOROCUPRATE Usage And Synthesis

Chemical Properties

clear orange to brown-red solution

Uses

Lithium tetrachlorocuprate acts as catalyst used to couple alkyl halides with alkyl Grignard reagents, Used to halogenate pyrimidine nucleosides. Organic soluble copper catalyst used in catalytic quantities to improve the efficiency of halide and allylic acetate displacements with Grignard reagent, it is used in stoichiometric amounts to open epoxides and aziridines.

LITHIUM TETRACHLOROCUPRATESupplier

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