(9-(4-BROMOPHENYL))-3,6-DI-TERT-BUTYL-9H-CARBAZOLE Chemical Properties

Melting point:

154.0 to 158.0 °C

Boiling point:

520.0±42.0 °C(Predicted)

Density 

1.18±0.1 g/cm3(Predicted)

storage temp. 

Sealed in dry,Room Temperature

form 

powder to crystal

color 

White to Almost white

λmax

343nm(CH2Cl2)(lit.)

Safety Information

HS Code 

2933.99.8290

(9-(4-BROMOPHENYL))-3,6-DI-TERT-BUTYL-9H-CARBAZOLE Usage And Synthesis

Synthesis

General method: 3,6-di-tert-butylcarbazole (0.5 mmol) and p-bromofluorobenzene (2.0 mmol) were mixed in a solvent (2 mL) in the presence of a base (2.0 mmol). The reaction mixture was heated to the indicated temperature under air atmosphere for 24 hours. Upon completion of the reaction, the mixture was poured into brine (15 mL) and extracted with dichloromethane (3 x 15 mL). The organic phases were combined, concentrated under reduced pressure and the target product 9-(4-bromophenyl)-3,6-di-tert-butyl-9H-carbazole was isolated and purified by chromatography on a 200-300 mesh silica gel column.

References

[1] Synthesis (Germany), 2016, vol. 48, # 5, p. 737 - 750

(9-(4-BROMOPHENYL))-3,6-DI-TERT-BUTYL-9H-CARBAZOLE(601454-33-5)Related Product Information

• 9-(3,5-Dibromophenyl)-9H-carbazole
• 1-bromo-6-carbazol-9-ylhexane