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TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE

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TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Basic information

Product Name:
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Synonyms:
  • tris(3,5-dimethylphenyl)-phosphin
  • TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
  • TRIS(3,5-XYLYL)PHOSPHINE
  • TRI(3,5-XYLYL)PHOSPHINE
  • Tris(3,5-dimethylphenyl)phosphine,98%
  • TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE, 97+%
  • Tri(3,5-dimethylphenyl)phosphine
  • Tris(3,5-dimethylphenyl)phosphineTris(3,5-xylyl)phosphine
CAS:
69227-47-0
MF:
C24H27P
MW:
346.44
EINECS:
624-162-2
Product Categories:
  • Aryl Phosphine
  • Achiral Phosphine
  • Ligand
  • Catalysis and Inorganic Chemistry
  • Phosphine Ligands
  • organophosphorus ligand
  • Phosphorus Compounds
Mol File:
69227-47-0.mol
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TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Chemical Properties

Melting point:
160-165 °C
Boiling point:
474.1±45.0 °C(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
color 
white
EPA Substance Registry System
Phosphine, tris(3,5-dimethylphenyl)- (69227-47-0)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
26-36/37/39-22
WGK Germany 
3
TSCA 
Yes
HS Code 
29310099

MSDS

  • Language:English Provider:ACROS
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TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

Catalyst for:

  • Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones
  • Highly selective rhodium-catalyzed hydrogenation reactions
  • Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes

Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes

Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis

TRIS(3,5-DIMETHYLPHENYL)PHOSPHINESupplier

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