ChemicalBook > Product Catalog > Analytical Chemistry > Analysis reagents > General Analytical Reagents > (-)-TROGER'S BASE
(-)-TROGER'S BASE
(-)-TROGER'S BASE Basic information
- Product Name:
- (-)-TROGER'S BASE
- Synonyms:
-
- (5S,11S)-(-)-2,8-DIMETHYL-6H,12H-5,11-METHANODIBENZO[B,F][1,5]DIAZOCIN
- (-)-TROGER'S BASE
- (S)-2,8-dimethyl-5,11-methanodibenzo (B,F)(1,5)diazocin
- (-)-TRGER'S BASE
- 6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine, 2,8-dimethyl-, (5R,11R)-
- CAS:
- 14645-24-0
- MF:
- C17H18N2
- MW:
- 250.34
- Mol File:
- 14645-24-0.mol
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(-)-TROGER'S BASE Chemical Properties
- Melting point:
- 127-131 °C
- Boiling point:
- 461.0±45.0 °C(Predicted)
- Density
- 1.21±0.1 g/cm3(Predicted)
- pka
- 4.53±0.20(Predicted)
- optical activity
- [α]20/D 283±4°, c = 0.3% in hexane
- BRN
- 88611
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Safety Information
- Hazard Codes
- Xn,N,Xi
- Risk Statements
- 22-50/53-36/37/38
- Safety Statements
- 26-60-61
- RIDADR
- UN 2811 6.1/PG 3
- WGK Germany
- 3
- F
- 10-23
MSDS
- Language:English Provider:SigmaAldrich
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(-)-TROGER'S BASE Usage And Synthesis
Uses
It was used as an standard analyte for testing the enantioseparation capability of the chiral stationary phase column; in a study to understand the covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column.
General Description
Tr?ger base (TB) is a chiral heterocyclic amine with chirality due to the presence of two stereogenic nitrogen atoms.