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BORANE-TRIPHENYLPHOSPHINE COMPLEX

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BORANE-TRIPHENYLPHOSPHINE COMPLEX Basic information

Product Name:
BORANE-TRIPHENYLPHOSPHINE COMPLEX
Synonyms:
  • TRIPHENYLPHOSPHINE BORANE
  • BORANE-TRIPHENYLPHOSPHINE
  • BORANE-TRIPHENYLPHOSPHINE COMPLEX
  • Borane-triphenylphosphine complex,97%
  • Boran-Triphenylphosphine Complex
  • TriphenylphosphinBorane
  • Borane triphenylphosphine complex 97%
  • Borane triphenylphosph
CAS:
2049-55-0
MF:
C18H18BP
MW:
276.12
Product Categories:
  • B (Classes of Boron Compounds)
  • Boranes
Mol File:
2049-55-0.mol
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BORANE-TRIPHENYLPHOSPHINE COMPLEX Chemical Properties

Melting point:
189-191 °C (lit.)
storage temp. 
Refrigerator
form 
Powder
color 
White
Sensitive 
Air & Moisture Sensitive
Stability:
Stable. Incompatible with acids, oxidizing agents, acid chlorides, alcohols. May decompose on exposure to air and moisture.
CAS DataBase Reference
2049-55-0(CAS DataBase Reference)
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Safety Information

RIDADR 
UN3396
WGK Germany 
3
HazardClass 
4.3
PackingGroup 
II
HS Code 
29319019

MSDS

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BORANE-TRIPHENYLPHOSPHINE COMPLEX Usage And Synthesis

Chemical Properties

white crystals with an unpleasant smell

Uses

Reactant for:

  • C-P cross coupling with aryl iodides
  • Synthesis of N-heterocyclic carbene borane complexes via Lewis base exchange
  • Catalyst-free alcoholysis to deprotect phosphane-boranes
  • Undergoing heterolytic activation
  • Deprotection via reactions with resin-supported amines
  • Insertion of overcrowded silylene into hydroboranes

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