XPhos Pd G3
XPhos Pd G3 Basic information
- Product Name:
- XPhos Pd G3
- Synonyms:
-
- XPhos Pd G3
- Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- (2-Dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
- Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [XPhos Palladacycle]
- Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%
- XPhos G3
- METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II), MIN. 98
- METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)DICHLOROMETHANEADDUCT(XPHOS Pd G3)
- CAS:
- 1445085-55-1
- MF:
- C46H62NO3PPdS
- MW:
- 846.46
- Product Categories:
-
- Buchwald Ligands&Precatalysts
- Buchwald Precatalysts Series
- Pd
- Mol File:
- 1445085-55-1.mol
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XPhos Pd G3 Chemical Properties
- Melting point:
- 146-151°C (decomposition)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- white to off-white
- InChI
- InChI=1S/C33H49P.C12H9N.CH4O3S.Pd/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;1-6,8-9,13H;1H3,(H,2,3,4);/q;-2;;+2
- InChIKey
- VXKANHUGMZCOIM-UHFFFAOYSA-N
- SMILES
- P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C
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XPhos Pd G3 Usage And Synthesis
Reaction
Palladium precatalyst for facile C-N cross-coupling reactions.
Uses
XPhos Pd G3 may be used in the following reactions:
- Cyanation reaction of heterocyclic halides.
- Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents.
- Coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides.
Uses
Convenient dosable form of XPhos-Pd-G3.
0.025 mmoles per capsule (1EA = 0.025 mmoles)
General Description
XPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XPhos Pd G3 is an excellent reagent for Suzuki cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
XPhos Pd G3Supplier
Henan Runfeng Catalyst Co. LTD Gold
- Tel
- 15560227177
- sales@runcatalysts.cn
Wu Han Lbpchem Chemical Co., Ltd. Gold
- Tel
- 02763499399 13797220777
- lpbchem@163.com
Wuhan phosphine biologic Pharmaceutical Co., LTD Gold
- Tel
- 15102702255 15102702255
- 35729423@qq.com
Wuhan Jiade Ruifeng New Materials Co., Ltd Gold
- Tel
- 18271874579
- 2176439072@qq.com
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. Gold
- Tel
- 0371-0371-65511006 18625597674
- sales@kingorgchem.com
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XPhos Pd G3(1445085-55-1)Related Product Information
- tBuXPhos-Pd-G3
- XantPhos Pd G4
- Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- SPhos Palladacycle Gen. 4
- XPhos Pd G4
- Xantphos Pd G3
- BrettPhos Pd G3
- XPhos Pd G2
- RuPhos Pd G1 Methyl t--Butyl Ether Adduct
- SPhos Pd G2
- BrettPhosPalladacycle
- Palladacycle Gen. 3
- t-BuXphos Palladacycle Gen. 4
- RuPhos Palladacycle Gen. 4
- t-BuBrettPhos Palladacycle Gen. 3
- SPhos Pd G3
- SPhos Pd G1, Methyl t-Butyl Ether Adduct
- RuPhos Pd G2