Basic information Uses Reaction Safety Supplier Related

Bis(N,N'-di-t-butylacetamidinato)nickel(II)

Basic information Uses Reaction Safety Supplier Related

Bis(N,N'-di-t-butylacetamidinato)nickel(II) Basic information

Product Name:
Bis(N,N'-di-t-butylacetamidinato)nickel(II)
Synonyms:
  • Bis(N,N'-di-t-butylacetaMidinato)nickel(II), (99.999%-Ni) PURATREM
  • Bis(N,N'-di-t-butylacetamidinato)nickel
  • (99.999%-Ni) PURATREM
  • Bis(N,N'-di-t-butylacetamidinato)nickel(Ni(t-Bu-Me-AMD)2)
  • Bis(N,N'-di-t-butylacetamidinato)nickel(II)
  • Bis(N,N''-di-t-butylacetamidinato)nickel(II),
  • Bis(N,N'-di-t-butylacetamidinato)nickel(II)
CAS:
940895-79-4
MF:
C20H42N4Ni
MW:
397.28
Mol File:
940895-79-4.mol
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Bis(N,N'-di-t-butylacetamidinato)nickel(II) Chemical Properties

Melting point:
95-96°C
form 
crystal
color 
dark, purple-black
Sensitive 
air sensitive, moisture sensitive
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Bis(N,N'-di-t-butylacetamidinato)nickel(II) Usage And Synthesis

Uses

CVD/ALD precursor for the preparation of nickel nitride (NiNx) films.
CVD/ALD precursor for the preparation of nickel sulfide (NiSx) films co-deposited by H2S.

Reaction

  1. Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products.
  2. Catalyst precursor, with AgSbF6, for the asymmetric carbonylene reaction.
  3. Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals.

Bis(N,N'-di-t-butylacetamidinato)nickel(II)Supplier

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