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Potassium sodium tartrate tetrahydrate

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Potassium sodium tartrate tetrahydrate Basic information

Product Name:
Potassium sodium tartrate tetrahydrate
Synonyms:
  • Sosiumpotassiumtartrate
  • POTASSIUM SODIUM TARTRATE REAGENT (ACS)
  • POTASSIUM SODIUM TARTRATE TETRAHYDRATE, PH HELV
  • POTASSIUM SODIUM TARTRATE TETRAHYDRATE, REAGENTPLUS TM, >= 99%
  • PotassiumSodium(+)-TartrateA.R.
  • PotassiumSodiumTartrateFcc
  • PotassiumSodium(+)TartrateGr-(RochelleSalt)
  • PotassiumSodium(+)TartrateGr
CAS:
6381-59-5
MF:
C4H12KNaO10
MW:
282.22
EINECS:
613-385-0
Product Categories:
  • salt of an organic acid
Mol File:
6381-59-5.mol
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Potassium sodium tartrate tetrahydrate Chemical Properties

Melting point:
70-80 °C
alpha 
22.1 º (c=10, water)
Boiling point:
220°C
Density 
1.05 g/mL at 20 °C
refractive index 
22 ° (C=10, H2O)
storage temp. 
Store at +5°C to +30°C.
solubility 
H2O: 1 M at 20 °C, clear, colorless
form 
Solid
color 
White semi-transparent
PH
7.0-8.5 (25℃, 50mg/mL in H2O)
Odor
Odorless
PH Range
6.0 - 8.5
optical activity
[α]20/D +28.0 to +30.0°
Water Solubility 
630 g/L (20 ºC)
λmax
λ: 260 nm Amax: 0.026
λ: 280 nm Amax: 0.022
Merck 
14,7670
BRN 
6113568
LogP
-1.426 (est)
CAS DataBase Reference
6381-59-5(CAS DataBase Reference)
NIST Chemistry Reference
Sodium potassium tartrate tetrahydrate(6381-59-5)
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Safety Information

Risk Statements 
22-35
Safety Statements 
22-24/25-45-36/37/39-26
WGK Germany 
3
TSCA 
Yes
HS Code 
2918 13 00

MSDS

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Potassium sodium tartrate tetrahydrate Usage And Synthesis

Chemical Properties

white semi-transparent crystals

Uses

Constituent of Fehling's solution

Uses

Potassium sodium tartrate tetrahydrate has been used in the preparation of Lowry reagent for the determination of microsomal protein concentration in rat hepatic microsomes by Lowry method. It may be used as a constituent to prepare DNS (3,5- dinitrosalicylic acid) reagent and Fehling′s solution B, which are used in the determination of reducing sugar.

Uses

Potassium sodium tartrate tetrahydrate has been used in the preparation of 3,5-dinitrosalicylic acid solution used in the determination of the reducing sugar.

Preparation

Potassium sodium tartrate tetrahydrate is obtained by the follow steps:The starting material is tartar with a minimum tartaric acid content 68 %. This is first dissolved in water or in the mother liquor of a previous batch. It is then basified with hot saturated sodium hydroxide solution to pH 8, decolorized with activated charcoal, and chemically purified before being filtered. The filtrate is evaporated to 42 °Bé at 100 °C, and passed to granulators in which Seignette's salt crystallizes on slow cooling. The salt is separated from the mother liquor by centrifugation, accompanied by washing of the granules.

General Description

Potassium sodium tartrate tetrahydrate is a ferroelectric crystal with a high piezoelectric effect and electromechanical coupling coefficient.

Biochem/physiol Actions

Potassium sodium tartrate tetrahydrate might be used as a buffering agent in cosmetic products. It is also used as a food additive. Certain studies show that it produces acute renal toxicity in rabbits and dogs.

Purification Methods

Recrystallise it from distilled water (solubility: 0.4mL/g at 100o, 0.7mL/g at 14o). [Beilstein 3 IV 1223.]

Potassium sodium tartrate tetrahydrate Preparation Products And Raw materials

Raw materials

Preparation Products

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