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5-Bromo-3-pyridinecarboxaldehyde

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5-Bromo-3-pyridinecarboxaldehyde Basic information

Product Name:
5-Bromo-3-pyridinecarboxaldehyde
Synonyms:
  • CHEMBRDG-BB 4011095
  • AURORA KA-3030
  • 5-BROMO-PYRIDINE-3-CARBALDEHYDE
  • 5-BROMOPYRIDINE-3-CARBOXALDEHYDE
  • 5-BROMONICOTINALDEHYDE
  • 3-BROMOPYRIDINE-5-CARBALDEHYDE
  • 3-BROMOPYRIDINE-5-CARBOXALDEHYDE
  • 5-BROMO-3-PYRIDINECARBOXALDEHYDE
CAS:
113118-81-3
MF:
C6H4BrNO
MW:
186.01
EINECS:
628-546-0
Product Categories:
  • C6Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Halogenated
  • Pyridine
  • Heterocyclic Building Blocks
  • Heterocycle-Pyridine series
  • pharmacetical
  • Aldehydes
  • Pyridines
  • Building Blocks
Mol File:
113118-81-3.mol
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5-Bromo-3-pyridinecarboxaldehyde Chemical Properties

Melting point:
98-102 °C
Boiling point:
251.1±20.0 °C(Predicted)
Density 
1.683±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
1.07±0.20(Predicted)
form 
Crystalline Powder
color 
White to off-white
Sensitive 
Air Sensitive
InChI
InChI=1S/C6H4BrNO/c7-6-1-5(4-9)2-8-3-6/h1-4H
InChIKey
NGUVGKAEOFPLDT-UHFFFAOYSA-N
SMILES
C1=NC=C(Br)C=C1C=O
CAS DataBase Reference
113118-81-3(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
22-36/38-43
Safety Statements 
26-36/37/39
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
2933399990
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5-Bromo-3-pyridinecarboxaldehyde Usage And Synthesis

Synthesis

5-Bromo-3-pyridinecarboxaldehyde can be used as a pharmaceutical and chemical synthesis intermediate. In the existing technology, its synthesis method is to use 3,5-dibromo pyridine as raw material and exchange it with butyllithium bromide under ultra-low temperature (-78°C) conditions to prepare 5-Bromo-3-pyridinecarboxaldehyde. Or use 3,5-dibromopyridine as raw material and combine butyllithium and n-butylmagnesium chloride at -15°C to synthesize the product.

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