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Triphenylantimony

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Triphenylantimony Basic information

Product Name:
Triphenylantimony
Synonyms:
  • Triphenyl antimonide
  • TriphenylantiMony(II
  • Triphenylstiban
  • riphenylantimony
  • Trifenylstibin
  • Triphenylstibane
  • Triphenyl-stibane
  • triphenyl-stibin
CAS:
603-36-1
MF:
C18H15Sb
MW:
353.07
EINECS:
210-037-6
Product Categories:
  • organoantimony compound
  • Classes of Metal Compounds
  • Sb (Antimony) Compounds
  • Semimetal Compounds
Mol File:
603-36-1.mol
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Triphenylantimony Chemical Properties

Melting point:
52-54 °C(lit.)
Boiling point:
377 °C(lit.)
Density 
1,434 g/cm3
refractive index 
1.6948
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
<0.001g/l
form 
crystal
Specific Gravity
1.4343
color 
off-white
Water Solubility 
INSOLUBLE
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
3608108
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
603-36-1(CAS DataBase Reference)
NIST Chemistry Reference
Stibine, triphenyl-(603-36-1)
EPA Substance Registry System
Stibine, triphenyl- (603-36-1)
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Safety Information

Hazard Codes 
Xn,N
Risk Statements 
20/22-51/53
Safety Statements 
61
RIDADR 
UN 3467 6.1/PG 3
WGK Germany 
2
RTECS 
WJ1400000
TSCA 
Yes
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29310095

MSDS

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Triphenylantimony Usage And Synthesis

Chemical Properties

off-white powder

Uses

Stibonium salts, cocatalyst in converting trienes to aromatics and hydroaromatics, react with nitricsulfuric acid to give trinitro derivatives, polymerization inhibitor, lubricating-oil additive.

General Description

Atomic number of base material: 51 Antimony

Safety Profile

Poison by ingestion and intraperitoneal routes. Flammable when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use water, foam, mist. When heated to decomposition it emits toxic fumes of Sb. See also ANTIMONY COMPOUNDS.

Purification Methods

Recrystallise Ph3Sb from acetonitrile [Hayes et al. J Am Chem Soc 107 1346 1985]. [Beilstein 16 H 891, 16 IV 1198.]

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