ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Basic information
- Product Name:
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
- Synonyms:
-
- (R)-SHIP
- (S)-SHIP
- PHENYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE
- PHENYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE
- (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy,min.98%(R)-ShiP
- Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy
- (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
- CAS:
- 656233-53-3
- MF:
- C23H19O3P
- MW:
- 374.37
- Mol File:
- 656233-53-3.mol
More
Less
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Chemical Properties
- Melting point:
- 104-106°C
- Boiling point:
- 454.8±45.0 °C(Predicted)
- alpha
- +216° (c 0.5, CH2Cl2)
- form
- solid
- color
- white
- Sensitive
- moisture sensitive
More
Less
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Usage And Synthesis
Reaction
- Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
- Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.
- Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.
- Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
- Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Preparation Products And Raw materials
Raw materials
EtanolSodium hydroxideHydrochloric acidEthyl acetateTetrahydrofuranDichloromethanePETROLEUM ETHERTolueneTriethylamineAcetoneSodium bicarbonateHydrogen peroxidePalladiumHydrogenPhosphorus trichlorideNickelPhenolBenzyl chlorideEthyldiisopropylamineSodium bromideMethanesulfonic acid(S)-1,1'-SPIROBIINDANE-7,7'-DIOLBoron tribromide3-Hydroxybenzaldehyde(R)-1,1'-SPIROBIINDANE-7,7'-DIOLCinchonidineCALCIUM HYDRIDE
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXYSupplier
Shanghai Boyle Chemical Co., Ltd.
- Tel
- 021-50182298 021-50180596
- sales@boylechem.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
BeiJing Hwrk Chemicals Limted
- Tel
- 0757-86329057 18934348241
- sales4.gd@hwrkchemical.com
Daicel Chiral Technologies (China)CO.,LTD
- Tel
- 021-50460086-9 15921403865
- han_yajun@dctc.daicel.com
LaaJoo
- Tel
- 021-60702684 18516024827
- huang.jiayi@sinocompound.com